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Herein, a series of hyper\u2010cross\u2010linked polymers (HCPs) photocatalysts with different arenes monomers, including benzene (BE), diphenyl (DP), p\u2010terphenyl (TP), or p\u2010quaterphenyl (QP), were synthesized by simple Friedel\u2013Crafts alkylation reaction. Owing to the maximum monomer's conjunction degree and excellent oxygen (O<jats:sub>2<\/jats:sub>) adsorption capacity, QP\u2010HCPs exhibited highest photocatalytic activity for benzylamine oxidation coupled with H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> generation under the irradiation of 455\u2005nm Blue LED lamp. More than 99\u2009% of benzylamine could be converted to N\u2010benzylidenebenzylamine within 60\u2005min. In addition, nearly stoichiometric H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> was synchronously obtained with a high production rate of 9.3\u2005mmol g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup> h<jats:sup>\u22121<\/jats:sup>. Our work not only demonstrated that the photocatalytic activity of HCPs photocatalysts significantly depends on monomer's conjunction degree, but also provided a new strategy for converting solar energy to chemical energy.<\/jats:p>","DOI":"10.1002\/chem.202203607","type":"journal-article","created":{"date-parts":[[2022,12,8]],"date-time":"2022-12-08T22:09:46Z","timestamp":1670537386000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Enhanced Photocatalytic Activity of Hyper\u2010Cross\u2010Linked Polymers Toward Amines Oxidation Coupled with H<sub>2<\/sub>O<sub>2<\/sub> Generation through Extending Monomer's Conjugation Degree"],"prefix":"10.1002","volume":"29","author":[{"given":"Xinhao","family":"Nie","sequence":"first","affiliation":[{"name":"College of Science Hebei Agricultural University  Baoding 071001 P.R. 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