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The reaction of diazabutadiene\u2010supported yttrium hydride chelated a LiPPh<jats:sub>2<\/jats:sub> molecule (LY\u2009\u22c5\u2009THF)<jats:sub>2<\/jats:sub>(<jats:italic>\u03bc<\/jats:italic>\u2010H)<jats:sub>2<\/jats:sub>[<jats:italic>\u03bc<\/jats:italic>\u2010PPh<jats:sub>2<\/jats:sub>(Li)] (<jats:bold>1<\/jats:bold>, L=N,N\u2019\u2010di(2,6\u2010diisopropylphenyl)\u20101,4\u2010diazabutadiene) with P<jats:sub>4<\/jats:sub> gave two novel mixed Y\/Li multinuclear polyphosphorus complexes (LY\u2009\u22c5\u2009THF)<jats:sub>2<\/jats:sub>[<jats:italic>cyclo<\/jats:italic>\u2010P<jats:sub>3<\/jats:sub>]Li(THF)<jats:sub>3<\/jats:sub> (<jats:bold>2<\/jats:bold>) and [Li(THF)<jats:sub>4<\/jats:sub>]<jats:sup>+<\/jats:sup>[(LY\u2009\u22c5\u2009THF)<jats:sub>3<\/jats:sub>(<jats:italic>norborane<\/jats:italic>\u2010P<jats:sub>7<\/jats:sub>)Li(THF)]<jats:sup>\u2212<\/jats:sup> (<jats:bold>3<\/jats:bold>), accompanied with the elimination of diphosphorus compound Ph<jats:sub>2<\/jats:sub>PPPh<jats:sub>2<\/jats:sub> (<jats:bold>4<\/jats:bold>) and H<jats:sub>2<\/jats:sub>. However, the comparative reaction of yttrium hydride (LY\u2009\u22c5\u2009THF)<jats:sub>2<\/jats:sub>(<jats:italic>\u03bc<\/jats:italic>\u2010H)<jats:sub>2<\/jats:sub> with P<jats:sub>4<\/jats:sub> afforded a trinuclear yttrium pyramid\u2010P<jats:sub>4<\/jats:sub> complex (LY\u2009\u22c5\u2009THF)<jats:sub>3<\/jats:sub>(<jats:italic>\u03bc<\/jats:italic><jats:sub>3<\/jats:sub>\u2010P(PH)<jats:sub>3<\/jats:sub>) (<jats:bold>5<\/jats:bold>). Further investigations show that <jats:bold>5<\/jats:bold> cannot continuously react with LiPPh<jats:sub>2<\/jats:sub> to form <jats:bold>2<\/jats:bold> and <jats:bold>3<\/jats:bold>, and LiPPh<jats:sub>2<\/jats:sub> reacted with P<jats:sub>4<\/jats:sub> to form a <jats:italic>Zintl<\/jats:italic>\u2010P<jats:sub>7<\/jats:sub> lithium complex (TMEDA\u22c5Li)<jats:sub>3<\/jats:sub>(<jats:italic>Zintl<\/jats:italic>\u2010P<jats:sub>7<\/jats:sub>) (<jats:bold>6<\/jats:bold>) and <jats:bold>4<\/jats:bold>. These results indicated that the cooperation of Y\/Li for activation of P<jats:sub>4<\/jats:sub> is a key for the formation of <jats:bold>2<\/jats:bold> and <jats:bold>3<\/jats:bold>. All new compounds have been characterized by NMR spectroscopy and single\u2010crystal X\u2010ray diffraction studies.<\/jats:p>","DOI":"10.1002\/chem.202203679","type":"journal-article","created":{"date-parts":[[2023,1,9]],"date-time":"2023-01-09T22:18:35Z","timestamp":1673302715000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Cooperative Rare\u2010Earth\/Lithium\u2010Mediated Conversion of White Phosphorus"],"prefix":"10.1002","volume":"29","author":[{"given":"Qing","family":"You","sequence":"first","affiliation":[{"name":"Department of Chemistry Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Handan Road No 220 Shanghai 200433 P. R. 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