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The latter form various chain\u2010like building units with various degrees of branching. These modular units can be combined and arranged in different ways, which leads to closely related structures and several disordered configurations in each compound. As the material was obtained by high\u2010pressure high\u2010temperature synthesis, the disorder is most likely a consequence of quenching a high\u2010pressure phase with P(O,N)<jats:sub>5<\/jats:sub> trigonal bipyramids. Under ambient conditions, P atoms are expected to relax by moving to the centers of the face\u2010sharing tetrahedra that constitute the bipyramid. Diffraction patterns acquired with microfocused synchrotron radiation reveal that domains of both compounds are intergrown with H<jats:sub>3<\/jats:sub>P<jats:sub>8<\/jats:sub>O<jats:sub>8<\/jats:sub>N<jats:sub>9<\/jats:sub>, whose tetrahedral framework represents a cutout of the structures of both P<jats:sub>40<\/jats:sub>O<jats:sub>31<\/jats:sub>N<jats:sub>46<\/jats:sub> and P<jats:sub>74<\/jats:sub>O<jats:sub>59<\/jats:sub>N<jats:sub>84<\/jats:sub>. Powder diffraction patterns do not indicate any further phases.<\/jats:p>","DOI":"10.1002\/chem.202203892","type":"journal-article","created":{"date-parts":[[2023,1,31]],"date-time":"2023-01-31T22:21:46Z","timestamp":1675203706000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Modular Principle for Complex Disordered Tetrahedral Frameworks in Quenched High\u2010Pressure Phases of Phosphorus Oxide Nitrides"],"prefix":"10.1002","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8588-3265","authenticated-orcid":false,"given":"Daniel","family":"G\u00fcnther","sequence":"first","affiliation":[{"name":"Faculty for Chemistry and Mineralogy Institute for Mineralogy Crystallography and Materials Science Leipzig University  Scharnhorststra\u00dfe 20 04275 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dominik","family":"Baumann","sequence":"additional","affiliation":[{"name":"University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 (D) 81377 M\u00fcnchen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4571-8035","authenticated-orcid":false,"given":"Wolfgang","family":"Schnick","sequence":"additional","affiliation":[{"name":"University of Munich (LMU)  Butenandtstra\u00dfe 5\u201313 (D) 81377 M\u00fcnchen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0149-7066","authenticated-orcid":false,"given":"Oliver","family":"Oeckler","sequence":"additional","affiliation":[{"name":"Faculty for Chemistry and Mineralogy Institute for Mineralogy Crystallography and Materials Science Leipzig University  Scharnhorststra\u00dfe 20 04275 Leipzig Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,3,2]]},"reference":[{"volume-title":"Molecular Sieves","year":"1968","author":"Meier W. 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