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The donor\u2010Zn\u2010acceptor structure leads to visible light emission in the solid state, solution and polymer matrices with\n                    <jats:italic>\u03bb<\/jats:italic>\n                    <jats:sub>max<\/jats:sub>\n                    between 577\u2013657\u2005nm and, for zinc(II) complexes, unusually high radiative rate constants for triplet exciton decay of up to\n                    <jats:italic>k<\/jats:italic>\n                    <jats:sub>r<\/jats:sub>\n                    =1.5\u00d710\n                    <jats:sup>5<\/jats:sup>\n                    \u2005s\n                    <jats:sup>\u22121<\/jats:sup>\n                    at room temperature. Variable temperature and DFT\/MRCI studies show that a small energy gap between the\n                    <jats:sup>1\/3<\/jats:sup>\n                    LL\/LMCT states of only 79\u2005meV is responsible for efficient thermally activated delayed fluorescence (TADF). Time\u2010resolved luminescence and transient absorption studies confirm the occurrence of long\u2010lived, dominantly ligand\u2010to\u2010ligand charge transfer excited states in solution, allowing for application in Dexter energy transfer photocatalysis.\n                  <\/jats:p>","DOI":"10.1002\/chem.202203980","type":"journal-article","created":{"date-parts":[[2023,1,13]],"date-time":"2023-01-13T11:29:15Z","timestamp":1673609355000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["An Air\u2010 and Moisture\u2010stable Zinc(II) Carbene Dithiolate Dimer Showing Fast Thermally Activated Delayed Fluorescence and Dexter Energy Transfer Catalysis**"],"prefix":"10.1002","volume":"29","author":[{"given":"Ond\u0159ej","family":"Mr\u00f3zek","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Biology TU Dortmund University  Otto-Hahn-Str. 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mousree","family":"Mitra","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology TU Dortmund University  Otto-Hahn-Str. 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Bejamin","family":"Hupp","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology TU Dortmund University  Otto-Hahn-Str. 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Andrey","family":"Belyaev","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology TU Dortmund University  Otto-Hahn-Str. 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Nora","family":"L\u00fcdtke","sequence":"additional","affiliation":[{"name":"Institute of Theoretical and Computational Chemistry Heinrich Heine University D\u00fcsseldorf  40225 D\u00fcsseldorf Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dorothee","family":"Wagner","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Basel  4056 Basel Switzerland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cui","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Basel  4056 Basel Switzerland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Oliver S.","family":"Wenger","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Basel  4056 Basel Switzerland"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christel M.","family":"Marian","sequence":"additional","affiliation":[{"name":"Institute of Theoretical and Computational Chemistry Heinrich Heine University D\u00fcsseldorf  40225 D\u00fcsseldorf Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6952-7391","authenticated-orcid":false,"given":"Andreas","family":"Steffen","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Biology TU Dortmund University  Otto-Hahn-Str. 6 44227 Dortmund Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,3,15]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00573K"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08822"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703602"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.1c00353"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CY02336K"},{"key":"e_1_2_9_6_1","doi-asserted-by":"crossref","unstructured":"A. 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