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Yet, the atroposelective synthesis of these molecules remains a considerable challenge. In contrast to recent methods using more advanced chiral catalysts, a very simply accessed Jacobsen\u2010type chromium(III)\u2212salen complex was used here as a chiral enantiopure Lewis acid catalyst for a highly atroposelective Nenitzescu indole synthesis. Mild reaction conditions afforded various 5\u2010hydroxybenzo[\n                    <jats:italic>g<\/jats:italic>\n                    ]indoles in up to 97\u2009% yield. Moreover, through a simple work\u2010up, very high enantiomeric excesses of up to 99\u2009% could be obtained.\n                  <\/jats:p>","DOI":"10.1002\/chem.202300279","type":"journal-article","created":{"date-parts":[[2023,2,1]],"date-time":"2023-02-01T22:25:30Z","timestamp":1675290330000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Atroposelective Nenitzescu Indole Synthesis"],"prefix":"10.1002","volume":"29","author":[{"given":"Vinzenz","family":"Th\u00f6nni\u00dfen","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University  Landoltweg 1 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Iuliana L.","family":"Atodiresei","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University  Landoltweg 1 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4693-7240","authenticated-orcid":false,"given":"Frederic W.","family":"Patureau","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry RWTH Aachen University  Landoltweg 1 52074 Aachen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,3,8]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","first-page":"391","volume-title":"Name Reactions","author":"Li J. 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