{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:35:59Z","timestamp":1786977359831,"version":"build-2736575974"},"reference-count":83,"publisher":"Wiley","issue":"34","license":[{"start":{"date-parts":[[2023,5,2]],"date-time":"2023-05-02T00:00:00Z","timestamp":1682985600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["Sche 384\/40-1"],"award-info":[{"award-number":["Sche 384\/40-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2023,6,19]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Different cyclic (alkyl)(amino)carbenes (CAACs) were reacted with yellow arsenic. Several products [(CAAC\u2010n)\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc,\u03b7\n                    <jats:sup>1:1<\/jats:sup>\n                    \u2010As\n                    <jats:sub>2<\/jats:sub>\n                    )] (n=1 (\n                    <jats:bold>1<\/jats:bold>\n                    ), 4 (\n                    <jats:bold>2<\/jats:bold>\n                    )), [(CAAC\u20102)\n                    <jats:sub>3<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    ,\u03b7\n                    <jats:sup>1:1:1<\/jats:sup>\n                    \u2010As\n                    <jats:sub>4<\/jats:sub>\n                    )] (\n                    <jats:bold>3<\/jats:bold>\n                    ) and [(CAAC\u20103)\n                    <jats:sub>4<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>4<\/jats:sub>\n                    ,\u03b7\n                    <jats:sup>1:1:1:1<\/jats:sup>\n                    \u2010 As\n                    <jats:sub>8<\/jats:sub>\n                    )] (\n                    <jats:bold>6<\/jats:bold>\n                    ) were isolated due to the differing steric properties of\n                    <jats:bold>CAAC\u20101\u20104<\/jats:bold>\n                    . The products contain As\n                    <jats:sub>2<\/jats:sub>\n                    , As\n                    <jats:sub>4<\/jats:sub>\n                    or As\n                    <jats:sub>8<\/jats:sub>\n                    units and represent the first examples of CAACs\u2010substituted products of yellow arsenic. The reactivity of As\n                    <jats:sub>4<\/jats:sub>\n                    was compared with the reactivities of P\n                    <jats:sub>4<\/jats:sub>\n                    and the interpnictogen compound AsP\n                    <jats:sub>3<\/jats:sub>\n                    , which led to a series of phosphorus\u2010containing derivatives such as ([(CAAC\u20103)\n                    <jats:sub>3<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    ,\u03b7\n                    <jats:sup>1:1:1<\/jats:sup>\n                    \u2010P\n                    <jats:sub>4<\/jats:sub>\n                    )] (\n                    <jats:bold>4<\/jats:bold>\n                    ) and [(CAAC\u20103)\n                    <jats:sub>4<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>4<\/jats:sub>\n                    ,\u03b7\n                    <jats:sup>1:1:1:1<\/jats:sup>\n                    \u2010P\n                    <jats:sub>8<\/jats:sub>\n                    )] (\n                    <jats:bold>7<\/jats:bold>\n                    )) and [(CAAC\u20103)\n                    <jats:sub>3<\/jats:sub>\n                    (\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    ,\u03b7\n                    <jats:sup>1:1:1<\/jats:sup>\n                    \u2010AsP\n                    <jats:sub>3<\/jats:sub>\n                    )] (\n                    <jats:bold>5<\/jats:bold>\n                    ). The products were characterized by spectroscopic and crystallographic methods and DFT computations were performed to clarify their formation pathway.\n                  <\/jats:p>","DOI":"10.1002\/chem.202300280","type":"journal-article","created":{"date-parts":[[2023,4,4]],"date-time":"2023-04-04T15:33:25Z","timestamp":1680622405000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs)"],"prefix":"10.1002","volume":"29","author":[{"given":"Maria","family":"Haimerl","sequence":"first","affiliation":[{"name":"Institute for Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christoph","family":"Schwarzmaier","sequence":"additional","affiliation":[{"name":"Institute for Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christoph","family":"Riesinger","sequence":"additional","affiliation":[{"name":"Institute for Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1932-6647","authenticated-orcid":false,"given":"Alexey Y.","family":"Timoshkin","sequence":"additional","affiliation":[{"name":"Institute of Chemistry St. Petersburg State University  University emb. 7\/9 199034 St. Petersburg Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3553-1381","authenticated-orcid":false,"given":"Mohand","family":"Melaimi","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, San Diego UCSD-CNRS Joint Research Laboratory (IRL 3555)  La Jolla CA 92093-0358 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2623-2363","authenticated-orcid":false,"given":"Guy","family":"Bertrand","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry University of California, San Diego UCSD-CNRS Joint Research Laboratory (IRL 3555)  La Jolla CA 92093-0358 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institute for Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg 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