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Their stabilisation was achieved by using the bulky NHC IDipp (NHC=N\u2010heterocyclic carbene, IDipp=1,3\u2010bis(2,6\u2010diisopropylphenyl)\u2010imidazolin\u20102\u2010ylidene). The tripentelylgallanes and tripentelylalanes IDipp\u2009\u22c5\u2009Ga(PH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub> (<jats:bold>1\u2009a<\/jats:bold>), IDipp\u2009\u22c5\u2009Ga(AsH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub> (<jats:bold>1\u2009b<\/jats:bold>), IDipp\u2009\u22c5\u2009Al(PH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub> (<jats:bold>2\u2009a<\/jats:bold>) and IDipp\u2009\u22c5\u2009Al(AsH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub> (<jats:bold>2\u2009b<\/jats:bold>) were synthesised by salt metathesis of IDipp\u2009\u22c5\u2009ECl<jats:sub>3<\/jats:sub> (E=Al, Ga, In) with alkali metal pnictogenides such as NaPH<jats:sub>2<\/jats:sub>\/LiPH<jats:sub>2<\/jats:sub>\u2009\u22c5\u2009DME and KAsH<jats:sub>2<\/jats:sub>, respectively. Moreover, the detection of the first NHC\u2010stabilised tripentelylindiumane IDipp\u2009\u22c5\u2009In(PH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub> (<jats:bold>3<\/jats:bold>) was possible by multinuclear NMR spectroscopy. Initial investigations of the coordination ability of these compounds resulted in the successful isolation of the coordination compound [IDipp\u2009\u22c5\u2009Ga(PH<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010PH<jats:sub>2<\/jats:sub>{HgC<jats:sub>6<\/jats:sub>F<jats:sub>4<\/jats:sub>}<jats:sub>3<\/jats:sub>)] (<jats:bold>4<\/jats:bold>) by reaction of <jats:bold>1\u2009a<\/jats:bold> with (HgC<jats:sub>6<\/jats:sub>F<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>. The compounds were characterised by multinuclear NMR spectroscopy as well as single crystal X\u2010ray diffraction studies. Supporting computational studies highlight the electronic features of the products.<\/jats:p>","DOI":"10.1002\/chem.202300340","type":"journal-article","created":{"date-parts":[[2023,2,21]],"date-time":"2023-02-21T12:48:56Z","timestamp":1676983736000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["NHC\u2010Stabilised Parent Tripentelyltrielanes"],"prefix":"10.1002","volume":"29","author":[{"given":"Robert","family":"Szlosek","sequence":"first","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie Universit\u00e4t Regensburg  93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael A. 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