{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T18:02:57Z","timestamp":1789408977209,"version":"build-2803163510"},"reference-count":38,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2023,7,20]],"date-time":"2023-07-20T00:00:00Z","timestamp":1689811200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100008674","name":"Yazaki Memorial Foundation for Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008674","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008663","name":"Ogasawara Foundation for the Promotion of Science and Engineering","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100008663","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2023,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Nitrobenzene (NB) is a highly toxic chemical and a cause for concern to human health and the environment. Hence, it is worth designing new efficient and robust sensing platforms for NB. In this study, we present three newly synthesized luminescent silver cluster\u2010based coordination polymers, {[Ag<jats:sub>10<\/jats:sub>(S<jats:italic>t<\/jats:italic>Bu)<jats:sub>6<\/jats:sub>(CF<jats:sub>3<\/jats:sub>COO)<jats:sub>4<\/jats:sub>(hpbt)] (DMAc)<jats:sub>2<\/jats:sub>(CH<jats:sub>3<\/jats:sub>CN)<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (hpbt=<jats:italic>N,N,N\u2019,N'N\u201d,N\u201d<\/jats:italic>\u2010hexa(pyridine\u20104\u2010yl)benzene\u20101,3,5\u2010triamine), [Ag<jats:sub>12<\/jats:sub>(S<jats:italic>t<\/jats:italic>Bu)<jats:sub>6<\/jats:sub>(CF<jats:sub>3<\/jats:sub>COO)<jats:sub>6<\/jats:sub>(bpva)<jats:sub>3<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (bpva=9,10\u2010Bis(2\u2010(pyridin\u20104\u2010yl)vinyl)anthracene), and {[Ag<jats:sub>12<\/jats:sub>(S<jats:italic>t<\/jats:italic>Bu)<jats:sub>6<\/jats:sub>(CF<jats:sub>3<\/jats:sub>COO)<jats:sub>6<\/jats:sub>(bpb)(DMAc)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>] (DMAc)<jats:sub>2<\/jats:sub>}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (bpb=1,4\u2010Bis(4\u2010pyridyl)benzene) composed of Ag<jats:sub>10<\/jats:sub>, Ag<jats:sub>12<\/jats:sub> and Ag<jats:sub>12<\/jats:sub> cluster cores, respectively, connected by multidentate pyridine linkers. In addition, two new luminescent polymorphic silver(I)\u2010based coordination polymers, [Ag(CF<jats:sub>3<\/jats:sub>COO)(dpa)]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub> (dpa=9,10\u2010di(4\u2010pyridyl)anthracene) referred to as Agdpa (H) and Agdpa (R), where H and R denote hexagon\u2010 and rod\u2010like crystal shapes, respectively, have been prepared. The coordination polymers exhibit highly sensitive luminescence quenching effects to NB, attributed to the \u03c0\u2212\u03c0 stacking interactions between the polymers and NB as well as the electron\u2010withdrawing character of NB.<\/jats:p>","DOI":"10.1002\/chem.202300706","type":"journal-article","created":{"date-parts":[[2023,6,9]],"date-time":"2023-06-09T05:53:15Z","timestamp":1686289995000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Five Novel Silver\u2010Based Coordination Polymers as Photoluminescent Sensing Platforms for the Detection of Nitrobenzene"],"prefix":"10.1002","volume":"29","author":[{"given":"Taishu","family":"Sekine","sequence":"first","affiliation":[{"name":"Department of Applied Chemistry Faculty of Science Tokyo University of Science Kagurazaka  Shinjuku-ku Tokyo 162-8601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin","family":"Sakai","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Faculty of Science Tokyo University of Science Kagurazaka  Shinjuku-ku Tokyo 162-8601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusuke","family":"Horita","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Faculty of Science Tokyo University of Science Kagurazaka  Shinjuku-ku Tokyo 162-8601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haruna","family":"Mabuchi","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Faculty of Science Tokyo University of Science Kagurazaka  Shinjuku-ku Tokyo 162-8601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tsukasa","family":"Irie","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Faculty of Science Tokyo University of Science Kagurazaka  Shinjuku-ku Tokyo 162-8601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sakiat","family":"Hossain","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Faculty of Science Tokyo University of Science Kagurazaka  Shinjuku-ku Tokyo 162-8601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tokuhisa","family":"Kawawaki","sequence":"additional","affiliation":[{"name":"Department of Applied Chemistry Faculty of Science Tokyo University of Science Kagurazaka  Shinjuku-ku Tokyo 162-8601 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Subhabrata","family":"Das","sequence":"additional","affiliation":[{"name":"Chemical Materials Development Department Tanaka Kikinzoku Kogyo K.K. 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