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ZIF\u20108 was used to address the poor stability of the photosensitizer Rose Bengal (RB) encapsulation to synthesize RB@ZIF\u20108 NPs, which were doped into a composite film with poly (\u03f5\u2010caprolactone) (PCL) and polyvinyl alcohol\u2010quaternary ammonium chitosan (PVA\u2010QCS) as substrates to form composite films (PQZ). The composite films exhibited excellent photodynamic sterilization and good resistance to bacterial adhesion. The tensile strength of the film increased to 43.4\u2005MPa, which was approximately 1.8\u2005times that of the PCL film. With the addition of SiO<jats:sub>2<\/jats:sub> and RB@ZIF\u20108 NPs, the film exhibited water repellency and UV\u2010blocking properties. RAW264.7\u2005cells were selected using the MTT method to confirm that the composite films had excellent biocompatibility and had no significant inhibitory effect on cell growth and reproduction. 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