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The in\u2005situ formation of polyfluoroalkyl fluorosulfonates from commercially available fluorinated alcohols and economical sulfuryl fluoride is highly advantageous given that some polyfluoroalkyl halides are ozone\u2010depleting substances (ODS) regulated by the Montreal protocol. This general method is applied to the polyfluoroalkylation of a variety of sulfonamides,\n                    <jats:italic>N<\/jats:italic>\n                    \u2010sulfonyl carbamates and phthalimide with a wide tolerance of functional groups. 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