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The tether between the sulfonamide and the aryl group can be varied to access dihydroacridine\u2010, dibenzazepine\u2010, or dibenzazocine scaffolds. While substitution on the aniline portion is limited to electron\u2010neutral\u2010 or electron\u2010poor groups, a broader range of functional groups are tolerated on the\n                    <jats:italic>ortho<\/jats:italic>\n                    \u2010aryl substituent and site selective C\u2212NAr bond formation can be achieved. Preliminary mechanistic investigations suggest that medium\u2010ring formation occurs via radical reactive intermediates.\n                  <\/jats:p>","DOI":"10.1002\/chem.202301141","type":"journal-article","created":{"date-parts":[[2023,4,13]],"date-time":"2023-04-13T15:23:51Z","timestamp":1681399431000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Iodine(III)\u2010Mediated Oxidation of Anilines to Construct Dibenzazepines**"],"prefix":"10.1002","volume":"29","author":[{"given":"Carmen Margaret","family":"White","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Illinois Chicago  845\u2005W Taylor St. MC 111 Chicago IL 60607 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Naranchimeg","family":"Zorigt","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Illinois Chicago  845\u2005W Taylor St. MC 111 Chicago IL 60607 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tianning","family":"Deng","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Illinois Chicago  845\u2005W Taylor St. MC 111 Chicago IL 60607 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7001-342X","authenticated-orcid":false,"given":"Tom G.","family":"Driver","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Illinois Chicago  845\u2005W Taylor St. MC 111 Chicago IL 60607 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,5,11]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1056\/NEJMoa053107"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmcl.2014.11.025"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-819210-8.00003-5"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jm501100b"},{"key":"e_1_2_8_6_1","unstructured":"\u00a0"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1038\/sj.bjp.0707253"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527664450.ch8"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2md00290f"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm301013n"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40120-018-0111-2"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1111\/ane.13248"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bioorg.2021.105230"},{"key":"e_1_2_8_14_1","unstructured":"For reviews see:"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60287a006"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.2174\/1385272825999210104222338"},{"key":"e_1_2_8_17_2","first-page":"533","volume-title":"Prog. 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