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A series of mixed\u2010donor pincer\u2010ligated Mn(II) complexes, (<jats:sup>tBu2<\/jats:sup>PN<jats:sup><jats:italic>3<\/jats:italic><\/jats:sup>N<jats:sup>Pyz<\/jats:sup>)MnX<jats:sub>2<\/jats:sub> [<jats:italic>\u03ba<jats:sup>P<\/jats:sup>,\u03ba<jats:sup>N<\/jats:sup>,\u03ba<\/jats:italic><jats:sup><jats:italic>N<\/jats:italic><\/jats:sup>\u2010(<jats:italic>N<\/jats:italic>\u2010(di\u2010<jats:italic>tert<\/jats:italic>\u2010butylphosphaneyl)\u20106\u2010(1<jats:italic>H<\/jats:italic>\u2010pyrazol\u20101\u2010yl)pyridin\u20102\u2010amine)MnX<jats:sub>2<\/jats:sub>] {X=Cl (<jats:bold>Mn2<\/jats:bold>), X=Br (<jats:bold>Mn3<\/jats:bold>), X=I (<jats:bold>Mn4<\/jats:bold>)} were synthesized and characterized. Amongst the Mn(II) complexes, (<jats:bold>Mn2<\/jats:bold>, <jats:bold>Mn3<\/jats:bold>, <jats:bold>Mn4<\/jats:bold>) and Mn(I) complex, (<jats:sup>tBu2<\/jats:sup>PN<jats:sup><jats:italic>3<\/jats:italic><\/jats:sup>N<jats:sup>Pyz<\/jats:sup>)Mn(CO)<jats:sub>2<\/jats:sub>Br (<jats:bold>Mn1<\/jats:bold>) screened; the <jats:bold>Mn1<\/jats:bold> acts as an efficient catalyst for the chemoselective C=C bond reduction in <jats:italic>\u03b1<\/jats:italic>,<jats:italic>\u03b2<\/jats:italic>\u2010unsaturated ketones. Various synthetically important functionalities like halides, methoxy, trifluoromethyl, benzyloxy, nitro, amine, and unconjugated alkene and alkyne groups, including heteroarenes, were compatible and provided saturated ketones in excellent yields (up to 97\u2009%). A preliminary mechanistic study highlighted the crucial role of metal\u2013ligand (M\u2013L) cooperation through the dearomatization\u2010aromatization process in catalyst <jats:bold>Mn1<\/jats:bold> for the chemoselective C=C bond transfer hydrogenation.<\/jats:p>","DOI":"10.1002\/chem.202301174","type":"journal-article","created":{"date-parts":[[2023,5,16]],"date-time":"2023-05-16T09:50:30Z","timestamp":1684230630000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Manganese(I)\u2010Catalyzed Chemoselective Transfer Hydrogenation of the C=C Bond in Conjugated Ketones at Room Temperature"],"prefix":"10.1002","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2442-8741","authenticated-orcid":false,"given":"Dipesh M.","family":"Sharma","sequence":"first","affiliation":[{"name":"Organic Chemistry Division CSIR \u2013 National Chemical Laboratory (CSIR\u2013NCL)  Dr. Homi Bhabha Road Pune 411 008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0847-2339","authenticated-orcid":false,"given":"Anand B.","family":"Shabade","sequence":"additional","affiliation":[{"name":"Organic Chemistry Division CSIR \u2013 National Chemical Laboratory (CSIR\u2013NCL)  Dr. Homi Bhabha Road Pune 411 008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2841-0197","authenticated-orcid":false,"given":"Rajesh G.","family":"Gonnade","sequence":"additional","affiliation":[{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"},{"name":"Centre for Material Characterization CSIR \u2013 National Chemical Laboratory (CSIR\u2013NCL)  Dr. Homi Bhabha Road Pune India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9257-5236","authenticated-orcid":false,"given":"Benudhar","family":"Punji","sequence":"additional","affiliation":[{"name":"Organic Chemistry Division CSIR \u2013 National Chemical Laboratory (CSIR\u2013NCL)  Dr. Homi Bhabha Road Pune 411 008 India"},{"name":"Academy of Scientific and Innovative Research (AcSIR)  Ghaziabad 201002 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,6,23]]},"reference":[{"key":"e_1_2_10_1_1","unstructured":"\u00a0"},{"key":"e_1_2_10_2_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1600-0773.1996.tb00181.x"},{"key":"e_1_2_10_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bmc.2005.10.019"},{"key":"e_1_2_10_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/jm2005546"},{"key":"e_1_2_10_5_2","unstructured":"P. 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