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The reactions are triggered by [Zn<jats:sup>2+<\/jats:sup>\u2010O<jats:sup>\u2212<\/jats:sup>\u22c5]<jats:sup>+<\/jats:sup> or by the low\u2010valence Zn<jats:sup>+<\/jats:sup> through oxygen ion transfer or electron transfer to SO<jats:sub>2<\/jats:sub>, respectively. The NO<jats:sub>x<\/jats:sub><jats:sup>\u2212<\/jats:sup> ligands intervene in the oxidation only when sulfur dioxide is converted to SO<jats:sub>3<\/jats:sub><jats:sup>\u2212<\/jats:sup> or SO<jats:sub>2<\/jats:sub><jats:sup>\u2212<\/jats:sup>, leading to the formation of zinc sulfate and zinc sulfite coordinated to nitrate or nitrite anions. 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