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Compound <jats:bold>2<\/jats:bold> eliminated [ZnH<jats:sub>2<\/jats:sub>] giving diamido germylene <jats:bold>1<\/jats:bold> at 60\u2009\u00b0C. Compound <jats:bold>2<\/jats:bold> and deuterated analogue <jats:bold>2\u2010<jats:italic>d<\/jats:italic><\/jats:bold><jats:sub><jats:bold>2<\/jats:bold><\/jats:sub> exchanged with [ZnH<jats:sub>2<\/jats:sub>]<jats:sub>n<\/jats:sub> and [ZnD<jats:sub>2<\/jats:sub>]<jats:sub>n<\/jats:sub> in the presence of TMEDA to give a mixture of <jats:bold>2<\/jats:bold> and <jats:bold>2\u2010<jats:italic>d<\/jats:italic><\/jats:bold><jats:sub><jats:bold>2<\/jats:bold><\/jats:sub>. Compounds <jats:bold>2<\/jats:bold> and <jats:bold>4<\/jats:bold> reacted with carbon dioxide (1\u2005bar) at room temperature to form zincagermane diformate [(BDI\u2212H)Ge(OCHO)\u2010(OCHO)Zn(tmeda)] (<jats:bold>5<\/jats:bold>) and formate bridged digermylene [({BDI}Ge)<jats:sub>2<\/jats:sub>(\u03bc\u2010OCHO)]<jats:sup>+<\/jats:sup>[B(C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>(CF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>] (<jats:bold>6<\/jats:bold>) along with zinc formate [(tmeda)Zn(\u03bc\u2010OCHO)<jats:sub>3<\/jats:sub>Zn(tmeda)][B(C<jats:sub>6<\/jats:sub>H<jats:sub>3<\/jats:sub>(CF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>] (<jats:bold>7<\/jats:bold>), respectively. The hydridic nature of the Ge\u2212H and Zn\u2212H bonds in <jats:bold>2<\/jats:bold> and <jats:bold>4<\/jats:bold> was probed by reactions with Br\u00f6nsted and Lewis acids.<\/jats:p>","DOI":"10.1002\/chem.202301496","type":"journal-article","created":{"date-parts":[[2023,6,13]],"date-time":"2023-06-13T07:40:22Z","timestamp":1686642022000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Heterobimetallic Hydrides with a Germanium(II)\u2010Zinc Bond"],"prefix":"10.1002","volume":"29","author":[{"given":"Pritam","family":"Mahawar","sequence":"first","affiliation":[{"name":"Institute for Inorganic Chemistry RWTH Aachen University  52056 Aachen Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Thayalan","family":"Rajeshkumar","sequence":"additional","affiliation":[{"name":"CNRS INSA UPS UMR 5215 LPCNO Universit\u00e9 de Toulouse  35 Avenue de Rangueil 31077 Toulouse 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