{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T16:14:13Z","timestamp":1760285653578,"version":"build-2065373602"},"reference-count":62,"publisher":"Wiley","issue":"57","license":[{"start":{"date-parts":[[2023,9,11]],"date-time":"2023-09-11T00:00:00Z","timestamp":1694390400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21671086 and 21761013"],"award-info":[{"award-number":["21671086 and 21761013"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100013254","name":"National College Students Innovation and Entrepreneurship Training Program","doi-asserted-by":"publisher","award":["202210407005X"],"award-info":[{"award-number":["202210407005X"]}],"id":[{"id":"10.13039\/501100013254","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2023,10,13]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The combination of chirality and phase\u2010transition materials has broad application prospects. Therefore, based on the quasi\u2010spherical theory and the thought strategy of introducing chirality, we have successfully synthesized a pair of chiral enantiomeric ligands (<jats:italic>R<\/jats:italic>\/<jats:italic>S<\/jats:italic>)\u2010triethyl\u2010(2\u2010hydroxypropyl)ammonium iodide, which can be combined with a tin hexachloride anion to obtain a pair of new organic\u2013inorganic hybrid enantiomeric high\u2010temperature plastic phase\u2010transition materials: (<jats:italic>R<\/jats:italic>\/<jats:italic>S<\/jats:italic>)\u2010[CH<jats:sub>3<\/jats:sub>CH(OH)CH<jats:sub>2<\/jats:sub>N(CH<jats:sub>2<\/jats:sub>CH<jats:sub>3<\/jats:sub>)<jats:sub>3<\/jats:sub>]<jats:sub>2<\/jats:sub>SnCl<jats:sub>6<\/jats:sub> (<jats:bold>1\u2010R<\/jats:bold>\/<jats:bold>1\u2010S<\/jats:bold>), which have a high temperature phase transition of <jats:italic>T<\/jats:italic><jats:sub>c<\/jats:sub>=384\u2005K, crystallize in the <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub> chiral space group at room temperature, and have obvious CD signals. In addition, compounds <jats:bold>1\u2010R<\/jats:bold> and <jats:bold>1\u2010S<\/jats:bold> have a good low\u2010loss dielectric switch and broadband gap. This work is conducive to the research into chiral high\u2010temperature reversible plastic phase\u2010transition materials, and promotes the development of multi\u2010functional phase\u2010transition materials.<\/jats:p>","DOI":"10.1002\/chem.202301499","type":"journal-article","created":{"date-parts":[[2023,7,26]],"date-time":"2023-07-26T05:53:58Z","timestamp":1690350838000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Zero\u2010Dimensional Sn\u2010Based Enantiomeric Phase\u2010Transition Materials with High\u2010Tc and Dielectric Switching"],"prefix":"10.1002","volume":"29","author":[{"given":"Yan\u2010Le","family":"Huang","sequence":"first","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ting\u2010Ting","family":"Ying","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yi\u2010Ran","family":"Zhao","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yun\u2010Zhi","family":"Tang","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2029-3747","authenticated-orcid":false,"given":"Yu\u2010Hui","family":"Tan","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qiao\u2010Lin","family":"Li","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei\u2010Fei","family":"Liu","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ming\u2010Yang","family":"Wan","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Fang\u2010Xin","family":"Wang","sequence":"additional","affiliation":[{"name":"Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Jiangxi University of Science and Technology  156 Hakka Avenue Jiangxi Ganzhou 341000 P. R. China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2023,9,11]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT03206A"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC08693G"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT03948B"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201411005"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b03424"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c01069"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-00875-3"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2022.108114"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC06408A"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CE00009A"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202102990"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.129.047602"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1MA01108A"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c03309"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c03486"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b05037"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c02580"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202103268"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201501026"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904305"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CE01153G"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC01345A"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/asia.202100837"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cplett.2018.11.017"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC02085D"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00308C"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC05512E"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07055"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202201005"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.0c00113"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TC05800A"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CC03857D"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000290"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TC04479E"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105744"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2022.121254"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.2c01047"},{"key":"e_1_2_8_38_1","volume":"32","author":"Wang C. F.","year":"2022","journal-title":"Adv. Funct. Mater."},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c05108"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00886"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202007660"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202204135"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0035793"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.1817866116"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c02290"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC02547J"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1QM01157J"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-30085-1"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC01675J"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10539"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b08817"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA10947A"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10249"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00677"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11665"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201505224"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-019-1042-5"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.2c00780"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03710"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b07009"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1080\/01411594.2016.1212194"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b00228"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202301499","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T15:39:34Z","timestamp":1760283574000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202301499"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,9,11]]},"references-count":62,"journal-issue":{"issue":"57","published-print":{"date-parts":[[2023,10,13]]}},"alternative-id":["10.1002\/chem.202301499"],"URL":"https:\/\/doi.org\/10.1002\/chem.202301499","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"type":"print","value":"0947-6539"},{"type":"electronic","value":"1521-3765"}],"subject":[],"published":{"date-parts":[[2023,9,11]]},"assertion":[{"value":"2023-05-11","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2023-09-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202301499"}}