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Its iron(II) complex facilitates asymmetric direct hydrogenation of ketones without the participation of extra strong\u2010field ligand such as CO and isocyanide. Hydride donor lithium aluminum hydride (LAH) converted non\u2010reactive Fe(II) species to reactive Fe(II) hydride species. With this catalyst, various chiral alcohols including the intermediate for montelukast could be prepared with satisfactory yields and enantioinduction.<\/jats:p>","DOI":"10.1002\/chem.202301609","type":"journal-article","created":{"date-parts":[[2023,7,24]],"date-time":"2023-07-24T11:41:04Z","timestamp":1690198864000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["A Tetradentate Ligand Enables Iron\u2010Catalyzed Asymmetric Hydrogenation of Ketones in a CO\u2010 or Isocyanide\u2010Free Fashion"],"prefix":"10.1002","volume":"29","author":[{"given":"Lei","family":"Yang","sequence":"first","affiliation":[{"name":"Department of chemistry the Guangdong Provincial Key Laboratory of Catalysis Southern University of Science and Technology  1088 Xueyuan Road Shenzhen 518055 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xuefeng","family":"Tan","sequence":"additional","affiliation":[{"name":"Department of Chemistry City University of Hong Kong Kowloon Tong  Hong Kong SAR China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Menglong","family":"Zhao","sequence":"additional","affiliation":[{"name":"Department of chemistry the Guangdong Provincial Key Laboratory of Catalysis Southern University of Science and Technology  1088 Xueyuan Road Shenzhen 518055 China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3328-3265","authenticated-orcid":false,"given":"Jialin","family":"Wen","sequence":"additional","affiliation":[{"name":"Department of chemistry the Guangdong Provincial Key Laboratory of Catalysis Southern University of Science and Technology  1088 Xueyuan Road Shenzhen 518055 China"},{"name":"Current address: Jiangsu Hengrui Pharmaceuticals Co.  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