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The resulting library of cationic compounds [{CpMo(CO)\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc,\u03b7\n                    <jats:sup>2\u2009:\u20092<\/jats:sup>\n                    \u2010EPR)]\n                    <jats:sup>+<\/jats:sup>\n                    (R=Mes (2,4,6\u2010C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>2<\/jats:sub>\n                    Me\n                    <jats:sub>3<\/jats:sub>\n                    ), CH\n                    <jats:sub>3<\/jats:sub>\n                    , CPh\n                    <jats:sub>3<\/jats:sub>\n                    , SnMe\n                    <jats:sub>3<\/jats:sub>\n                    ) represents formally inorganic diazonium homologs which are stabilized by transition metal units. Modifying the steric and electronic properties of the electrophile drastically impacts the respective P\u2212R bond lengths and is accompanied by increasing (SnMe\n                    <jats:sub>3<\/jats:sub>\n                    &gt;CPh\n                    <jats:sub>3<\/jats:sub>\n                    &gt;CH\n                    <jats:sub>3<\/jats:sub>\n                    ) dynamic behavior in solution. In contrast to the well\u2010studied organic analogs, the prepared compounds are stable at room temperature. The subsequent reaction of the model substrate [{CpMo(CO)\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>2<\/jats:sub>\n                    (\u03bc,\u03b7\n                    <jats:sup>2\u2009:\u20092<\/jats:sup>\n                    \u2010P\n                    <jats:sub>2<\/jats:sub>\n                    Me)][OTf] ([OTf]\n                    <jats:sup>\u2212<\/jats:sup>\n                    =[CF\n                    <jats:sub>3<\/jats:sub>\n                    SO\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) with different N\u2010heterocyclic carbenes (NHCs) leads to an addition at the unsubstituted P atom which is also predicted by computational methods. NMR spectroscopy confirms the formation of two isomers\n                    <jats:italic>sync\/gauche<\/jats:italic>\n                    \u2010[{CpMo(CO)\n                    <jats:sub>2<\/jats:sub>\n                    }(\u03bc,\u03b7\n                    <jats:sup>2\u2009:\u20091<\/jats:sup>\n                    \u2010P(NHC)PMe){CpMo(CO)\n                    <jats:sub>2<\/jats:sub>\n                    }][OTf]. X\u2010ray crystallographic characterization and additional DFT calculations shed light on the spatial arrangement as well as on the possible formation pathways of the isomers.\n                  <\/jats:p>","DOI":"10.1002\/chem.202301974","type":"journal-article","created":{"date-parts":[[2023,7,26]],"date-time":"2023-07-26T10:44:38Z","timestamp":1690368278000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Synthesis and Reactivity of Hetero\u2010Pnictogen Diazonium Analogs Stabilized by Transition Metal Units"],"prefix":"10.1002","volume":"29","author":[{"given":"Lisa","family":"Zimmermann","sequence":"first","affiliation":[{"name":"Department of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christoph","family":"Riesinger","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G\u00e1bor","family":"Bal\u00e1zs","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg 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