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However, the corresponding manufacturing processes generally suffer from a deep reliance on hazardous reagents, inputs of immense energy, emissions of toxic pollutants, and the generation of substantial waste, which have negative impacts on the environment. In this context, sustainability and safety concerns provide a consistent impetus for the urgent overall improvement of phosphorus cycles. In this Concept, we present an overview of the most recent growth in photo\u2010 and electrochemical synthesis of P<jats:sub>1<\/jats:sub> organo\u2010compounds from P<jats:sub>4<\/jats:sub>, with special emphasis on sustainable features. The key aspects of innovations regarding activation mode and mechanism have been comprehensively analyzed. A preliminary look at the possible future direction of development is also provided.<\/jats:p>","DOI":"10.1002\/chem.202302142","type":"journal-article","created":{"date-parts":[[2023,9,6]],"date-time":"2023-09-06T05:34:31Z","timestamp":1693978471000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Sustainable Photo\u2010 and Electrochemical Transformation of White Phosphorous (P<sub>4<\/sub>) into P<sub>1<\/sub> Organo\u2010Compounds"],"prefix":"10.1002","volume":"29","author":[{"given":"Yan","family":"Liu","sequence":"first","affiliation":[{"name":"Henan International Joint Laboratory of Rare Earth Composite Material College of Materials Engineering Henan University of Engineering  Zhengzhou 451191 P. R. China"},{"name":"Green Catalysis Center College of Chemistry Zhengzhou University  Zhengzhou 450001 P. R. 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