{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T14:37:35Z","timestamp":1786977455521,"version":"build-2736575974"},"reference-count":55,"publisher":"Wiley","issue":"72","license":[{"start":{"date-parts":[[2023,11,6]],"date-time":"2023-11-06T00:00:00Z","timestamp":1699228800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2023,12,22]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    During the investigation of the binary system Be\u2212Ru two new phases \u2013 Be\n                    <jats:sub>7<\/jats:sub>\n                    Ru\n                    <jats:sub>4<\/jats:sub>\n                    and Be\n                    <jats:sub>12<\/jats:sub>\n                    Ru\n                    <jats:sub>7<\/jats:sub>\n                    \u2013 with similar compositions (63.6 at. % Be and 63.2 at. % Be, respectively), are discovered. They both represent new structural prototypes. The phases are located between Be\n                    <jats:sub>2<\/jats:sub>\n                    Ru (Fe\n                    <jats:sub>2<\/jats:sub>\n                    P\u2010type structure) and Be\n                    <jats:sub>3<\/jats:sub>\n                    Ru\n                    <jats:sub>2<\/jats:sub>\n                    (U\n                    <jats:sub>3<\/jats:sub>\n                    Si\n                    <jats:sub>2<\/jats:sub>\n                    \u2010type structure) in the phase diagram. This explains why their crystal structures, solved and refined from single crystal X\u2010ray diffraction data, are described as 2D intergrowth of Fe\n                    <jats:sub>2<\/jats:sub>\n                    P and U\n                    <jats:sub>3<\/jats:sub>\n                    Si\n                    <jats:sub>2<\/jats:sub>\n                    motives. The calculated electronic density of stats (DOS) reveals pronounced minima in the vicinity of the Fermi level for both compounds. Position\u2010space analysis of chemical bonding exhibits the formation of three\u2010 and four\u2010atomic polar bonds, involving both, Ru and Be, atoms, and a strong charge transfer from Be to the more electronegative Ru.\n                  <\/jats:p>","DOI":"10.1002\/chem.202302301","type":"journal-article","created":{"date-parts":[[2023,9,23]],"date-time":"2023-09-23T06:34:07Z","timestamp":1695450847000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Charge Transfer in Be\u2212Ru Compounds"],"prefix":"10.1002","volume":"29","author":[{"given":"Laura","family":"Agnarelli","sequence":"first","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yurii","family":"Prots","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mitja","family":"Krnel","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eteri","family":"Svanidze","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Markus","family":"K\u00f6nig","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcus","family":"Schmidt","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ulrich","family":"Burkhardt","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andreas","family":"Leithe\u2010Jasper","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3891-9584","authenticated-orcid":false,"given":"Yuri","family":"Grin","sequence":"additional","affiliation":[{"name":"Chemische Metallkunde Max-Planck-Institut f\u00fcr Chemische Physik fester Stoffe  N\u00f6thnitzer Stra\u00dfe 40 01187 Dresden Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,11,6]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","first-page":"222","volume-title":"Comprehensive Inorganic Chemistry III (Third Edition)","author":"Wagner F. 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