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The approaches proposed ensure synthesis of substituted quinoline carboxylates and (indolin\u20102\u2010ylidene)acetates in good yields. Introduction of alkynones into the reaction with 2\u2032\u2010amino\u20102,2,2\u2010trifluoroacetophenones gives acyl substituted derivatives in good yields.<\/jats:p>","DOI":"10.1002\/chem.202302357","type":"journal-article","created":{"date-parts":[[2023,8,19]],"date-time":"2023-08-19T01:50:55Z","timestamp":1692409855000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Switchable Selectivity in the Annulation of <i>o<\/i>\u2010Trifluoroacetylanilines and Activated Terminal Alkynes Based on Transition Metal and Phosphine Catalysis"],"prefix":"10.1002","volume":"29","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3141-3599","authenticated-orcid":false,"given":"Alexander Yu.","family":"Mitrofanov","sequence":"first","affiliation":[{"name":"Department of Chemistry Lomonosov Moscow State University  Leninskie Gory, GSP-1 Moscow 119991 Russian Federation"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Arina V.","family":"Murashkina","sequence":"additional","affiliation":[{"name":"Department of Chemistry Lomonosov Moscow State University  Leninskie Gory, GSP-1 Moscow 119991 Russian Federation"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Konstantin A.","family":"Lyssenko","sequence":"additional","affiliation":[{"name":"Department of Chemistry Lomonosov Moscow State University  Leninskie Gory, GSP-1 Moscow 119991 Russian Federation"},{"name":"G.V. 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