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The cyclic carbodiphosphorane outperformed the other Lewis basic carbon species tested, including other zerovalent carbon compounds, phosphorus ylides, an\n                    <jats:italic>N<\/jats:italic>\n                    \u2010heterocyclic carbene, and an\n                    <jats:italic>N<\/jats:italic>\n                    \u2010heterocyclic olefin. Hydroborations of seven carbodiimides and nine isocyanates were performed at room temperature to form\n                    <jats:italic>N<\/jats:italic>\n                    \u2010boryl formamidine and\n                    <jats:italic>N<\/jats:italic>\n                    \u2010boryl formamide products. Intermolecular competition experiments demonstrated the selective hydroboration of alkyl isocyanates over carbodiimide and ketone substrates. DFT calculations support a proposed mechanism involving activation of pinacolborane by the carbodiphosphorane catalyst, followed by hydride transfer and B\u2212N bond formation.\n                  <\/jats:p>","DOI":"10.1002\/chem.202303095","type":"journal-article","created":{"date-parts":[[2023,10,17]],"date-time":"2023-10-17T14:14:10Z","timestamp":1697552050000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Carbodiimide and Isocyanate Hydroboration by a Cyclic Carbodiphosphorane Catalyst**"],"prefix":"10.1002","volume":"30","author":[{"given":"Ben A.","family":"Janda","sequence":"first","affiliation":[{"name":"Chemistry and Biochemistry Program Schmid College of Science and Technology Chapman University  450 North Center Street Orange CA 92866 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Julie A.","family":"Tran","sequence":"additional","affiliation":[{"name":"Chemistry and Biochemistry Program Schmid College of Science and Technology Chapman University  450 North Center Street Orange CA 92866 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel K.","family":"Chang","sequence":"additional","affiliation":[{"name":"Chemistry and Biochemistry Program Schmid College of Science and Technology Chapman University  450 North Center Street Orange CA 92866 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gabriela C.","family":"Nerhood","sequence":"additional","affiliation":[{"name":"Chemistry and Biochemistry Program Schmid College of Science and Technology Chapman University  450 North Center Street Orange CA 92866 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5718-6761","authenticated-orcid":false,"given":"O.","family":"Maduka Ogba","sequence":"additional","affiliation":[{"name":"Chemistry and Biochemistry Program Schmid College of Science and Technology Chapman University  450 North Center Street Orange CA 92866 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8447-905X","authenticated-orcid":false,"given":"Allegra L.","family":"Liberman\u2010Martin","sequence":"additional","affiliation":[{"name":"Chemistry and Biochemistry Program Schmid College of Science and Technology Chapman University  450 North Center Street Orange CA 92866 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2023,11,21]]},"reference":[{"key":"e_1_2_10_1_1","first-page":"13","author":"Hollingworth R. 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