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Immobilization of Pd(0) species was performed to give R\u2010P\u2010Pd\u2010PMO\u2010TMS: R=Ph (<jats:bold>2\u2009a<\/jats:bold>), <jats:italic>t<\/jats:italic>Bu (<jats:bold>3\u2009a<\/jats:bold>), respectively. The Pd(0) immobilized <jats:bold>2\u2009a<\/jats:bold> and <jats:bold>3\u2009a<\/jats:bold> were applicable as catalysts for Suzuki\u2010Miyaura cross\u2010coupling reactions of aryl chlorides with phenylboronic acid. It was revealed that <jats:bold>3\u2009a<\/jats:bold> bearing more electron\u2010donating <jats:italic>t<\/jats:italic>Bu groups exhibited higher catalytic activity. Various functional groups including both electron withdrawing and donating substituents were compatible in the system. The recyclability of <jats:bold>3\u2009a<\/jats:bold> was examined to support its moderate utility for the recycle use.<\/jats:p>","DOI":"10.1002\/chem.202303159","type":"journal-article","created":{"date-parts":[[2023,11,29]],"date-time":"2023-11-29T04:11:32Z","timestamp":1701231092000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Suzuki\u2010Miyaura Cross\u2010Coupling Reaction Using Palladium Catalysts Supported on Phosphine Periodic Mesoporous Organosilica"],"prefix":"10.1002","volume":"30","author":[{"given":"Kosuke","family":"Iizuka","sequence":"first","affiliation":[{"name":"Interdisciplinary Research Center for Catalytic Chemistry National Institute of Advanced Science and Technology (AIST)  1-1-1 Higashi Tsukuba Ibaraki 305-8565 Japan"},{"name":"Tokyo Institute of Technology School of Materials and Chemical Technology  2-12-1 Ookayama Meguro-ku Tokyo 152-8552 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yoshifumi","family":"Maegawa","sequence":"additional","affiliation":[{"name":"Toyota Central R&amp;D Labs., Inc.  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