{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T21:39:07Z","timestamp":1791668347641,"version":"4.3.4"},"reference-count":57,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2024,1,15]],"date-time":"2024-01-15T00:00:00Z","timestamp":1705276800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52162030"],"award-info":[{"award-number":["52162030"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2024,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>High\u2010efficacy recycling of spent lithium cobalt oxide (LiCoO<jats:sub>2<\/jats:sub>) batteries is one of the key tasks in realizing a global resource security strategy due to the rareness of lithium (Li) and cobalt (Co) resources. However, it is of great significance to develop the innovative recycle methods for spent LiCoO<jats:sub>2<\/jats:sub>, simultaneously realizing the efficient recovery of valuable elements and the regeneration of high\u2010performance LiCoO<jats:sub>2<\/jats:sub>. Herein, a novel strategy of regenerating LiCoO<jats:sub>2<\/jats:sub> cathode is proposed, which involves the preparation of micro\u2010spherical aluminum (Al)\u2010doped lithium\u2010lacked precursor (Li<jats:sub>2x<\/jats:sub>Co<jats:sub>1\u2212x\u2212y<\/jats:sub>Al<jats:sub>2\/3y<\/jats:sub>CO<jats:sub>3,<\/jats:sub> remarked as \u201cPLCAC\u201d) via ammonium bicarbonate coprecipitation. The comprehensive conditions affecting particle growth kinetics, morphology and particle size the has been investigated in detail by physical characterizations and electrochemical measurements. And the optimized Al\u2010doped LiCoO<jats:sub>2<\/jats:sub> materials with high\u2010density sphericity (LiCo<jats:sub>1\u2212z<\/jats:sub>Al<jats:sub>z<\/jats:sub>O<jats:sub>2<\/jats:sub>, remarked as \u201cLCAO\u201d) shows a high initial specific capacity of 161\u2005mAh\u2009g<jats:sup>\u22121<\/jats:sup> at 0.1\u2005C and excellent capacity retention of 99.5\u2009% within 100 cycles at 1\u2005C in the voltage range of 2.8 to 4.3\u2005V. Our work provides valuable insights into the featured design of LiCoO<jats:sub>2<\/jats:sub> precursors and cathode materials from spent LiCoO<jats:sub>2<\/jats:sub> batteries, potentially guaranteeing the high\u2010efficacy recycling and utilization of strategic resources.<\/jats:p>","DOI":"10.1002\/chem.202303424","type":"journal-article","created":{"date-parts":[[2023,12,20]],"date-time":"2023-12-20T07:06:13Z","timestamp":1703055973000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Short\u2010Process Regeneration of Highly Stable Spherical LiCoO<sub>2<\/sub> Cathode Materials from Spent Lithium\u2010Ion Batteries through Carbonate Precipitation"],"prefix":"10.1002","volume":"30","author":[{"given":"Jingjing","family":"He","sequence":"first","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"},{"name":"City College Kunming University of Science and Technology  Kunming 650500 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanpeng","family":"Cao","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0581-6677","authenticated-orcid":false,"given":"Xianshu","family":"Wang","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Zhao","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiemeng","family":"Huang","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Long","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhongren","family":"Zhou","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Dong","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yingjie","family":"Zhang","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ding","family":"Wang","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianguo","family":"Duan","sequence":"additional","affiliation":[{"name":"National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan Province Department Faculty of Metallurgical and Energy Engineering Kunming University of Science and Technology  Kunming 650093 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,15]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2020.228708"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2020.10.017"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.resconrec.2020.105219"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2018.08.041"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c06869"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm901452z"},{"key":"e_1_2_9_8_1","unstructured":"\u00a0"},{"key":"e_1_2_9_9_2","doi-asserted-by":"publisher","DOI":"10.3390\/met11010108"},{"key":"e_1_2_9_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00297E"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.164576"},{"key":"e_1_2_9_12_1","unstructured":"\u00a0"},{"key":"e_1_2_9_13_2","doi-asserted-by":"publisher","DOI":"10.1007\/s40831-019-00235-9"},{"key":"e_1_2_9_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00535"},{"key":"e_1_2_9_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC01077E"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2023.233094"},{"key":"e_1_2_9_17_2","doi-asserted-by":"publisher","DOI":"10.1039\/D3GC02987E"},{"key":"e_1_2_9_18_1","unstructured":"\u00a0"},{"key":"e_1_2_9_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c02854"},{"key":"e_1_2_9_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c09017"},{"key":"e_1_2_9_21_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10854-018-9870-x"},{"key":"e_1_2_9_22_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10854-018-8958-7"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.0c00610"},{"key":"e_1_2_9_24_1","unstructured":"\u00a0"},{"key":"e_1_2_9_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7TA07232E"},{"key":"e_1_2_9_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2015.10.135"},{"key":"e_1_2_9_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201900355"},{"key":"e_1_2_9_28_2","doi-asserted-by":"publisher","DOI":"10.1149\/2.0421910jes"},{"key":"e_1_2_9_29_2","doi-asserted-by":"publisher","DOI":"10.1088\/1674-1056\/27\/8\/088202"},{"key":"e_1_2_9_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2018.09.032"},{"key":"e_1_2_9_31_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0409-z"},{"key":"e_1_2_9_32_1","unstructured":"\u00a0"},{"key":"e_1_2_9_33_2","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.2c04665"},{"key":"e_1_2_9_34_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-018-0180-6"},{"key":"e_1_2_9_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.1c04338"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2014.08.108"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2014.02.100"},{"key":"e_1_2_9_38_1","unstructured":"\u00a0"},{"key":"e_1_2_9_39_2","doi-asserted-by":"publisher","DOI":"10.1149\/1.2711068"},{"key":"e_1_2_9_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm0102537"},{"key":"e_1_2_9_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2012.12.071"},{"key":"e_1_2_9_42_1","unstructured":"\u00a0"},{"key":"e_1_2_9_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsu.202300325"},{"key":"e_1_2_9_44_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-019-0409-z"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA09931G"},{"key":"e_1_2_9_46_1","first-page":"943","volume":"36","author":"Liu Q.","year":"2018","journal-title":"Nat. Energy"},{"key":"e_1_2_9_47_1","unstructured":"\u00a0"},{"key":"e_1_2_9_48_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2011.07.114"},{"key":"e_1_2_9_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2008.10.077"},{"key":"e_1_2_9_50_2","doi-asserted-by":"publisher","DOI":"10.1007\/s41918-018-0012-1"},{"key":"e_1_2_9_51_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.arabjc.2014.04.001"},{"key":"e_1_2_9_52_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2007.04.025"},{"key":"e_1_2_9_53_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.hydromet.2011.02.010"},{"key":"e_1_2_9_54_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.hydromet.2009.10.010"},{"key":"e_1_2_9_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.hydromet.2005.06.004"},{"key":"e_1_2_9_56_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1003-6326(11)61460-X"},{"key":"e_1_2_9_57_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2007.02.046"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202303424","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T21:36:40Z","timestamp":1760305000000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202303424"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,1,15]]},"references-count":57,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2024,3]]}},"alternative-id":["10.1002\/chem.202303424"],"URL":"https:\/\/doi.org\/10.1002\/chem.202303424","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,1,15]]},"assertion":[{"value":"2023-10-17","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-01-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202303424"}}