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Herein, we report a manganese catalyzed dehydrogenative coupling of glycerol with amines for the synthesis of substituted 2\u2010methylquinoxalines, 2\u2010ethylbenzimidazoles, and\n                    <jats:italic>\u03b1<\/jats:italic>\n                    \u2010aminoketones without any external oxidant. In these reactions, NHC\u2010based pincer manganese complex featuring a pyridine backbone displayed high catalytic activity and selectivity, in which hydrogen and water were produced as the only by\u2010products using glycerol as a C3 synthon.\n                  <\/jats:p>","DOI":"10.1002\/chem.202303481","type":"journal-article","created":{"date-parts":[[2024,1,19]],"date-time":"2024-01-19T02:27:17Z","timestamp":1705631237000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Manganese\u2010catalyzed Efficient Synthesis of\n                    <i>N<\/i>\n                    \u2010heterocycles and Aminoketones Using Glycerol as a C3 Synthon"],"prefix":"10.1002","volume":"30","author":[{"given":"Zeyuan","family":"Wei","sequence":"first","affiliation":[{"name":"Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Center of Basic Molecular Science (CBMS) Department of Chemistry Tsinghua University  Beijing 100084 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuofeng","family":"Ke","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering PCFM Lab Sun Yat-sen University  Guangzhou 510006 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yujie","family":"Wang","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Advanced Rare Earth Materials (Ministry of Education) Center of Basic Molecular Science (CBMS) Department of Chemistry Tsinghua University  Beijing 100084 China"},{"name":"State Key Laboratory of Antiviral Drugs Pingyuan Laboratory Henan Normal University  Xinxiang Henan 453007 P. 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