{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,2]],"date-time":"2026-06-02T21:56:12Z","timestamp":1780437372317,"version":"3.54.1"},"reference-count":109,"publisher":"Wiley","issue":"12","license":[{"start":{"date-parts":[[2024,1,8]],"date-time":"2024-01-08T00:00:00Z","timestamp":1704672000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["Sche 384\/41-1"],"award-info":[{"award-number":["Sche 384\/41-1"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2024,2,26]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The syntheses of novel N\u2010heterocyclic carbene (NHC) adducts of group 13, 14 and 15 element hydrides are reported. Salt metathesis reactions between NaPH<jats:sub>2<\/jats:sub> and IDipp\u2009\u22c5\u2009GeH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>OTf (<jats:bold>1<\/jats:bold>) (IDipp=1,3\u2010bis(2,6\u2010diisopropylphenyl)imidazol\u20102\u2010ylidene) led to mixtures of the two isomers IDipp\u2009\u22c5\u2009GeH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub> (<jats:bold>2\u2009a<\/jats:bold>) and IDipp\u2009\u22c5\u2009BH<jats:sub>2<\/jats:sub>GeH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub> (<jats:bold>2\u2009b<\/jats:bold>); by altering the reaction conditions an almost exclusive formation of <jats:bold>2\u2009b<\/jats:bold> was achieved. Attempts to purify mixtures of <jats:bold>2\u2009a<\/jats:bold> and <jats:bold>2\u2009b<\/jats:bold> by re\u2010crystallization from THF afforded a salt [IDipp\u2009\u22c5\u2009GeH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>\u2009\u22c5\u2009IDipp][PHGeH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>GeH<jats:sub>2<\/jats:sub>] (<jats:bold>4<\/jats:bold>) that contains the novel anionic cyclohexyl\u2010like inorganic heterocycle [PHGeH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>GeH<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>. In addition, the borane adducts IDipp\u2009\u22c5\u2009GeH<jats:sub>2<\/jats:sub>BH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>BH<jats:sub>3<\/jats:sub> (<jats:bold>3\u2009a<\/jats:bold>) and IDipp\u2009\u22c5\u2009BH<jats:sub>2<\/jats:sub>GeH<jats:sub>2<\/jats:sub>PH<jats:sub>2<\/jats:sub>BH<jats:sub>3<\/jats:sub> (<jats:bold>3\u2009b<\/jats:bold>) as even longer chain compounds were obtained from reactions of <jats:bold>2\u2009a<\/jats:bold>\/<jats:bold>2\u2009b<\/jats:bold> with H<jats:sub>3<\/jats:sub>B\u2009\u22c5\u2009SMe<jats:sub>2<\/jats:sub> and were studied by NMR spectroscopy. Accompanying DFT computations give insight into the mechanism and energetics associated with <jats:bold>2\u2009a<\/jats:bold>\/<jats:bold>2\u2009b<\/jats:bold> isomerization as well as their decomposition pathways.<\/jats:p>","DOI":"10.1002\/chem.202303680","type":"journal-article","created":{"date-parts":[[2023,11,27]],"date-time":"2023-11-27T18:43:28Z","timestamp":1701110608000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["NHC\u2010Stabilized Mixed Group 13\/14\/15 Element Hydrides"],"prefix":"10.1002","volume":"30","author":[{"given":"Matthias T.","family":"Ackermann","sequence":"first","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert","family":"Szlosek","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christoph","family":"Riesinger","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Seidl","sequence":"additional","affiliation":[{"name":"Institute of General and Theoretical Chemistry University of Innsbruck  Innrain 80\u201382 6020 Innsbruck Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1932-6647","authenticated-orcid":false,"given":"Alexey Y.","family":"Timoshkin","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Saint Petersburg State University  Universitetskaya emb. 7\/9 199034 St Petersburg Russia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric","family":"Rivard","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Alberta  11227 Saskatchewan Dr Edmonton Alberta T6G 2G2 Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2182-5020","authenticated-orcid":false,"given":"Manfred","family":"Scheer","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry University of Regensburg  Universit\u00e4tsstra\u00dfe 31 93053 Regensburg Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,1,8]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19260590907"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00401-X"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0065-3055(03)49006-0"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.04.010"},{"key":"e_1_2_9_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201504867"},{"key":"e_1_2_9_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201504867"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198912081"},{"key":"e_1_2_9_7_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19891010908"},{"key":"e_1_2_9_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9731837"},{"key":"e_1_2_9_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm00015a001"},{"key":"e_1_2_9_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201507084"},{"key":"e_1_2_9_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200901064"},{"key":"e_1_2_9_11_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200901064"},{"key":"e_1_2_9_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201203074"},{"key":"e_1_2_9_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705510"},{"key":"e_1_2_9_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.3c04179"},{"key":"e_1_2_9_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202301741"},{"key":"e_1_2_9_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00278"},{"key":"e_1_2_9_17_1","unstructured":"\u00a0"},{"key":"e_1_2_9_18_2","first-page":"250","volume-title":"New Aspects in Phosphorus Chemistry V","author":"Gates D. P.","year":"2005"},{"key":"e_1_2_9_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2013.10.005"},{"key":"e_1_2_9_20_1","unstructured":"\u00a0"},{"key":"e_1_2_9_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b07389"},{"key":"e_1_2_9_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201700829"},{"key":"e_1_2_9_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.201800202"},{"key":"e_1_2_9_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b08741"},{"key":"e_1_2_9_25_1","unstructured":"\u00a0"},{"key":"e_1_2_9_26_2","doi-asserted-by":"publisher","DOI":"10.1039\/C29690000775"},{"key":"e_1_2_9_27_2","doi-asserted-by":"publisher","DOI":"10.1515\/znb-1980-0402"},{"key":"e_1_2_9_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/om049558w"},{"key":"e_1_2_9_29_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3cc41897a"},{"key":"e_1_2_9_30_2","doi-asserted-by":"publisher","DOI":"10.1080\/10426507.2015.1128925"},{"key":"e_1_2_9_31_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6CC01885H"},{"key":"e_1_2_9_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201611509"},{"key":"e_1_2_9_32_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201611509"},{"key":"e_1_2_9_33_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201705644"},{"key":"e_1_2_9_33_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201705302"},{"key":"e_1_2_9_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT01119B"},{"key":"e_1_2_9_35_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201914644"},{"key":"e_1_2_9_35_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201914644"},{"key":"e_1_2_9_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201914986"},{"key":"e_1_2_9_36_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201914986"},{"key":"e_1_2_9_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.202100723"},{"key":"e_1_2_9_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CC03561H"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.200600210"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201902877"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9DT00608G"},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201910933"},{"key":"e_1_2_9_42_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201910933"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202012218"},{"key":"e_1_2_9_43_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202012218"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/cber.19751081002"},{"key":"e_1_2_9_45_1","unstructured":"\u00a0"},{"key":"e_1_2_9_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01163a083"},{"key":"e_1_2_9_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/C19670000249"},{"key":"e_1_2_9_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50057a010"},{"key":"e_1_2_9_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/J19680001675"},{"key":"e_1_2_9_50_2","first-page":"662","author":"Goddard N.","year":"1969","journal-title":"J. Chem. Soc. A"},{"key":"e_1_2_9_51_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202103780"},{"key":"e_1_2_9_52_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC06594K"},{"key":"e_1_2_9_53_1","unstructured":"\u00a0"},{"key":"e_1_2_9_54_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.123557"},{"key":"e_1_2_9_55_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja206738v"},{"key":"e_1_2_9_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4NR05125D"},{"key":"e_1_2_9_57_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.5016443"},{"key":"e_1_2_9_58_1","unstructured":"\u00a0"},{"key":"e_1_2_9_59_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20011203)40:23<4409::AID-ANIE4409>3.0.CO;2-F"},{"key":"e_1_2_9_59_3","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20011203)113:23<4541::AID-ANGE4541>3.0.CO;2-U"},{"key":"e_1_2_9_60_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200390054"},{"key":"e_1_2_9_61_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200600185"},{"key":"e_1_2_9_62_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209703"},{"key":"e_1_2_9_62_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201209703"},{"key":"e_1_2_9_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201310519"},{"key":"e_1_2_9_63_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201310519"},{"key":"e_1_2_9_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201505773"},{"key":"e_1_2_9_64_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201505773"},{"key":"e_1_2_9_65_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201608875"},{"key":"e_1_2_9_65_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201608875"},{"key":"e_1_2_9_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201707436"},{"key":"e_1_2_9_66_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201707436"},{"key":"e_1_2_9_67_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201914046"},{"key":"e_1_2_9_67_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201914046"},{"key":"e_1_2_9_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202013849"},{"key":"e_1_2_9_68_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202013849"},{"key":"e_1_2_9_69_1","unstructured":"For examples of heavy element LB\u2009\u22c5\u2009H2Tet-TetH2\u2009\u22c5\u2009LA adducts see:"},{"key":"e_1_2_9_70_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201103576"},{"key":"e_1_2_9_70_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201103576"},{"key":"e_1_2_9_71_2","doi-asserted-by":"publisher","DOI":"10.1021\/om400361n"},{"key":"e_1_2_9_72_1","doi-asserted-by":"publisher","DOI":"10.1039\/b915950a"},{"key":"e_1_2_9_73_1","unstructured":"\u00a0"},{"key":"e_1_2_9_74_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200901472"},{"key":"e_1_2_9_75_2","unstructured":"Note: the torsion angles appear also with the opposite sign due to the chain appearing in a mirrored position in the solid state (cf. Supporting Information)."},{"key":"e_1_2_9_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196507741"},{"key":"e_1_2_9_76_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19650771709"},{"key":"e_1_2_9_77_1","unstructured":"A possible mechanism under extrusion of PH3leading to the formation of4is described in the Supporting Information."},{"key":"e_1_2_9_78_1","unstructured":"\u00a0"},{"key":"e_1_2_9_79_2","doi-asserted-by":"publisher","DOI":"10.1002\/zaac.19855311216"},{"key":"e_1_2_9_80_2","unstructured":"CrysAlisPro (ROD) Rigaku Oxford Diffraction Poland (2021);"},{"key":"e_1_2_9_81_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767395007367"},{"key":"e_1_2_9_82_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889808042726"},{"key":"e_1_2_9_83_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_9_84_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_9_85_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_9_86_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_9_87_2","doi-asserted-by":"publisher","DOI":"10.1039\/b508541a"},{"key":"e_1_2_9_88_2","unstructured":"M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone B. Mennucci G.\u2005A. Petersson H. Nakatsuji M. Caricato X. Li H.\u2005P. Hratchian A.\u2005F. Izmaylov J. Bloino G. Zheng J.\u2005L. Sonnenberg M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai T. Vreven J.\u2005A. Montgomery Jr. J.\u2005E. Peralta F. Ogliaro M. Bearpark J.\u2005J. Heyd E. Brothers K.\u2005N. Kudin V.\u2005N. Staroverov T. Keith R. Kobayashi J. Normand K. Raghavachari A. Rendell J.\u2005C. Burant S.\u2005S. Iyengar J. Tomasi M. Cossi N. Rega J.\u2005M. Millam M. Klene J.\u2005E. Knox J.\u2005B. Cross V. Bakken C. Adamo J. Jaramillo R. Gomperts R.\u2005E. Stratmann O. Yazyev A.\u2005J. Austin R. Cammi C. Pomelli J.\u2005W. Ochterski R.\u2005L. Martin K. Morokuma V.\u2005G. Zakrzewski G.\u2005A. Voth P. Salvador J.\u2005J. Dannenberg S. Dapprich A.\u2005D. Daniels O. Farkas J.\u2005B. Foresman J.\u2005V. Ortiz J. Cioslowski D.\u2005J. Fox inGaussian 09 Vol. Revision E.01 Gaussian Inc. Wallingford CT 2013;"},{"key":"e_1_2_9_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/ci600510j"},{"key":"e_1_2_9_90_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1096-987X(199610)17:13<1571::AID-JCC9>3.0.CO;2-P"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202303680","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T19:27:54Z","timestamp":1760297274000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202303680"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,1,8]]},"references-count":109,"journal-issue":{"issue":"12","published-print":{"date-parts":[[2024,2,26]]}},"alternative-id":["10.1002\/chem.202303680"],"URL":"https:\/\/doi.org\/10.1002\/chem.202303680","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,1,8]]},"assertion":[{"value":"2023-11-06","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-01-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202303680"}}