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Opposed to most current protocols for electrode preparation, this work presents a one\u2010step binder\u2010 and additive\u2010free production of silver\u2010 and copper\u2010electroplated electrodes. Controlled adjustment of the preparation parameters allows for the tuning of catalyst morphology and its electrochemical properties. Upon optimization of the deposition protocol and carbon support, high faradaic efficiencies of 93\u2009% for the ECH of the Vitamin\u2005A\u2010 and E\u2010synthon 2\u2010methyl\u20103\u2010butyn\u20102\u2010ol (MBY) are achieved that can be maintained at current densities of 240\u2005mA\u2009cm<jats:sup>\u22122<\/jats:sup> and minimal catalyst loadings of 0.2\u2005mg\u2009cm<jats:sup>\u22122<\/jats:sup>, corresponding to an unmatched production rate of 1.47\u2005kg<jats:sub>MBE<\/jats:sub>\u2009g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>. For a continuous hydrogenation process, the protocol can be directly transferred into a single\u2010pass operation mode giving a production rate of 1.38\u2005kg<jats:sub>MBE<\/jats:sub>\u2009g<jats:sub>cat<\/jats:sub><jats:sup>\u22121<\/jats:sup>\u2009h<jats:sup>\u22121<\/jats:sup>. Subsequently, the substrate spectrum was extended to a total of 17\u2005different C\u2212C\u2212, C\u2212O\u2212 and N\u2212O\u2212unsaturated compounds revealing the general applicability of the reported process. Our results lay an important groundwork for the development of electrochemical reactors and electrodes able to directly compete with the palladium\u2010based thermocatalytic state of the art.<\/jats:p>","DOI":"10.1002\/chem.202303808","type":"journal-article","created":{"date-parts":[[2023,12,15]],"date-time":"2023-12-15T13:53:08Z","timestamp":1702648388000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Electroplated Electrodes for Continuous and Mass\u2010Efficient Electrochemical Hydrogenation"],"prefix":"10.1002","volume":"30","author":[{"given":"Jonas","family":"Wolf","sequence":"first","affiliation":[{"name":"Abteilung Elektrosynthese Fraunhofer Institut f\u00fcr Umwelt-, Sicherheits-und Energietechnik UMSICHT  Osterfelder Stra\u00dfe 3 46047 Oberhausen Germany"},{"name":"Anorganische Chemie I Fakult\u00e4t f\u00fcr Chemie und Biochemie Ruhr-Universit\u00e4t Bochum Universit\u00e4tsstra\u00dfe 150  44780 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