{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,13]],"date-time":"2026-09-13T05:08:42Z","timestamp":1789276122475,"version":"build-2803163510"},"reference-count":84,"publisher":"Wiley","issue":"34","license":[{"start":{"date-parts":[[2024,5,17]],"date-time":"2024-05-17T00:00:00Z","timestamp":1715904000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2024,6,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Although it is well\u2010known that the Lewis acidity of Metal\u2010Organic Frameworks (MOFs) can effectively enhance their catalytic activity in organic transformations, access to these Lewis\u2010acidic sites remains a key hurdle to widespread applications of Lewis\u2010acidic catalysis by MOFs. Easy accessibility of strong Lewis acidic sites onto 2D MOFs by using proper activation methods can be a cornerstone in attaining desired catalytic performance. Herein, we report a new 2D chemically stable MOF, <jats:bold>IITKGP\u201060<\/jats:bold>, which displayed excellent framework robustness over a wide pH range (2\u201312). Benefiting from the abundant open metal sites (OMSs) and framework robustness, the catalytic activity of the developed material was explored in one\u2010pot three\u2010component Strecker reaction and Knoevenagel condensation reaction. Moreover, the developed catalyst is superior in catalyzing the reactions involving sterically hindered substrate (1\u2010naphthaldehyde) with high turnover number. A comparative catalytic study was conducted using different activation methods (chloroform and methanol exchanged activated samples), highlighting the significant effect of activation methods on its catalytic performances. The sustainable synthetic pathway under <jats:italic>solvent\u2010free<\/jats:italic> conditions for a broad scope of substrates using low catalyst loading and excellent recyclability made the developed pH\u2010stable framework a promising heterogeneous catalyst.<\/jats:p>","DOI":"10.1002\/chem.202400375","type":"journal-article","created":{"date-parts":[[2024,4,16]],"date-time":"2024-04-16T02:44:35Z","timestamp":1713235475000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":25,"title":["Variation in Catalytic Efficacies of a 2D pH\u2010Stable MOF by Altering Activation Methods"],"prefix":"10.1002","volume":"30","author":[{"given":"Janaki","family":"Behera","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur 721302, WB India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arun","family":"Pal","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur 721302, WB India"},{"name":"School of Science Constructor University  Campus Ring 1 28759 Bremen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rupam","family":"Sahoo","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur 721302, WB India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6571-8705","authenticated-orcid":false,"given":"Madhab C.","family":"Das","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology Kharagpur  Kharagpur 721302, WB India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,5,17]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4TA04001E"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA00816F"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/b807080f"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2023.111561"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.2174\/2212796814999200918175018"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matpr.2019.08.106"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.2174\/2212796817666230626120825"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215301"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c02275"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202207197"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2019.10.012"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200190s"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2019.213023"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213892"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/B916295J"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00243"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CS00997K"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.9b00823"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00094C"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2009.05.019"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QI00206J"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CE01782G"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00603E"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NR09064F"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200304e"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.10.002"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4EE00143E"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/natrevmats.2016.78"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202001611"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI01138J"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c10973"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.213998"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.141795"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201903912"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201705328"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00685"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201803157"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202203706"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202206283"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.3c00633"},{"key":"e_1_2_9_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.05.001"},{"key":"e_1_2_9_42_1","unstructured":"R. Sahoo B. Pramanik S. Mondal M.\u2005C. Das Small2309281. https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202309281"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c03152"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c01793"},{"key":"e_1_2_9_45_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60475F"},{"key":"e_1_2_9_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr200101d"},{"key":"e_1_2_9_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00930A"},{"key":"e_1_2_9_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI00167H"},{"key":"e_1_2_9_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1DT00202C"},{"key":"e_1_2_9_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202304581"},{"key":"e_1_2_9_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2023.110528"},{"key":"e_1_2_9_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.3c02435"},{"key":"e_1_2_9_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.3c00892"},{"key":"e_1_2_9_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202101692"},{"key":"e_1_2_9_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201405167"},{"key":"e_1_2_9_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201703384"},{"key":"e_1_2_9_57_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.144340"},{"key":"e_1_2_9_58_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1239872"},{"key":"e_1_2_9_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201600243"},{"key":"e_1_2_9_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00842"},{"key":"e_1_2_9_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006102"},{"key":"e_1_2_9_62_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compositesb.2022.110174"},{"key":"e_1_2_9_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201905650"},{"key":"e_1_2_9_64_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802632"},{"key":"e_1_2_9_65_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja308229p"},{"key":"e_1_2_9_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2019.117214"},{"key":"e_1_2_9_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CE02660E"},{"key":"e_1_2_9_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00733"},{"key":"e_1_2_9_69_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.0c03736"},{"key":"e_1_2_9_70_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c01049"},{"key":"e_1_2_9_71_1","first-page":"3","volume":"7","author":"Liang B.","year":"2020","journal-title":"Natl. Sci."},{"key":"e_1_2_9_72_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA05383B"},{"key":"e_1_2_9_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202103723"},{"key":"e_1_2_9_74_1","doi-asserted-by":"publisher","DOI":"10.1002\/admi.202102560"},{"key":"e_1_2_9_75_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201900617"},{"key":"e_1_2_9_76_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA02684D"},{"key":"e_1_2_9_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c03561"},{"key":"e_1_2_9_78_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.02.008"},{"key":"e_1_2_9_79_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.201802059"},{"key":"e_1_2_9_80_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NR01827F"},{"key":"e_1_2_9_81_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214667"},{"key":"e_1_2_9_82_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00609E"},{"key":"e_1_2_9_83_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00395K"},{"key":"e_1_2_9_84_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b03307"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202400375","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T20:48:48Z","timestamp":1760302128000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202400375"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,5,17]]},"references-count":84,"journal-issue":{"issue":"34","published-print":{"date-parts":[[2024,6,17]]}},"alternative-id":["10.1002\/chem.202400375"],"URL":"https:\/\/doi.org\/10.1002\/chem.202400375","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,5,17]]},"assertion":[{"value":"2024-01-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-05-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202400375"}}