{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T03:49:23Z","timestamp":1789444163602,"version":"build-2803163510"},"reference-count":79,"publisher":"Wiley","issue":"27","license":[{"start":{"date-parts":[[2024,3,15]],"date-time":"2024-03-15T00:00:00Z","timestamp":1710460800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22025301, U23B20163, 22321003"],"award-info":[{"award-number":["22025301, U23B20163, 22321003"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2024,5,14]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The diatomic molecule PH is very reactive, and it serves as the parent compound for phosphinidenes featuring a monovalent phosphorus atom. Herein, we report the characterization and reactivity of a rare hydrogen\u2010bonded complex of PH. Specifically, the molecular complex between PH and HCl has been generated by photolysis of chlorophosphine (H<jats:sub>2<\/jats:sub>PCl) at 254\u2005nm in a solid Ar\u2010matrix at 10\u2005K. The IR spectrum of the complex HP\u22c5\u22c5\u22c5HCl and quantum chemical calculations at the UCCSD(T)\u2010F12a\/haTZ level consistently prove that the phosphorus atom acts as a hydrogen bond acceptor with a binding energy (<jats:italic>D<\/jats:italic><jats:sub>0<\/jats:sub>) of \u22120.6\u2005kcal\u2009mol<jats:sup>\u22121<\/jats:sup>. In line with the observed absorption at 341\u2005nm for the binary complex, the triplet phosphinidene PH undergoes prototype H\u2212Cl bond insertion by reformation of H<jats:sub>2<\/jats:sub>PCl upon photoexcitation at 365\u2005nm. However, this hydrogen\u2010bonded complex is unstable in the presence of N<jats:sub>2<\/jats:sub> and HCl, as both molecules prefers stronger interactions with HCl than PH in the observed complexes HP\u22c5\u22c5\u22c5HCl\u22c5\u22c5\u22c5N<jats:sub>2<\/jats:sub> and HP\u22c5\u22c5\u22c52HCl.<\/jats:p>","DOI":"10.1002\/chem.202400490","type":"journal-article","created":{"date-parts":[[2024,2,29]],"date-time":"2024-02-29T10:25:11Z","timestamp":1709202311000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Hydrogen\u2010Bonded Complex of the Parent Phosphinidene"],"prefix":"10.1002","volume":"30","author":[{"given":"Junjie","family":"Jiang","sequence":"first","affiliation":[{"name":"Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Fang","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Lu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weixing","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qi","family":"Yu","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4611-2094","authenticated-orcid":false,"given":"Xiaoqing","family":"Zeng","sequence":"additional","affiliation":[{"name":"Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,15]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11263"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b07069"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b11791"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2016.04.001"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b04232"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2017.10.009"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201804863"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202303283"},{"key":"e_1_2_8_10_1","unstructured":"\u00a0"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703629"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200462862"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b05464"},{"key":"e_1_2_8_14_1","unstructured":"\u00a0"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b01639"},{"key":"e_1_2_8_16_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0CP05254J"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CC08664H"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja0269892"},{"key":"e_1_2_8_19_1","unstructured":"\u00a0"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.3c00429"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.1c00017"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02256"},{"key":"e_1_2_8_23_1","unstructured":"\u00a0"},{"key":"e_1_2_8_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201703672"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202218587"},{"key":"e_1_2_8_26_2","doi-asserted-by":"publisher","DOI":"10.1021\/om100335j"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja4072699"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00355a004"},{"key":"e_1_2_8_29_1","unstructured":"\u00a0"},{"key":"e_1_2_8_30_2","doi-asserted-by":"publisher","DOI":"10.1038\/285156a0"},{"key":"e_1_2_8_31_2","doi-asserted-by":"publisher","DOI":"10.1029\/JC086iC12p11985"},{"key":"e_1_2_8_32_1","unstructured":"\u00a0"},{"key":"e_1_2_8_33_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41586-023-06616-1"},{"key":"e_1_2_8_34_2","first-page":"L9","volume":"230","author":"Guelin M.","year":"1990","journal-title":"Astron. Astrophys."},{"key":"e_1_2_8_35_1","unstructured":"\u00a0"},{"key":"e_1_2_8_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201700368"},{"key":"e_1_2_8_37_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1CP02860J"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c10003"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202217353"},{"key":"e_1_2_8_40_1","unstructured":"\u00a0"},{"key":"e_1_2_8_41_2","first-page":"6067","volume":"201","author":"Lammertsma K.","year":"1991","journal-title":"J. Org. Chem."},{"key":"e_1_2_8_42_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0301-0104(00)00349-9"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00014a013"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c12808"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja034388k"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1124022"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200806268"},{"key":"e_1_2_8_48_1","unstructured":"\u00a0"},{"key":"e_1_2_8_49_2","doi-asserted-by":"publisher","DOI":"10.1021\/jz502150d"},{"key":"e_1_2_8_50_2","doi-asserted-by":"publisher","DOI":"10.1039\/D2CP03434D"},{"key":"e_1_2_8_51_2","doi-asserted-by":"publisher","DOI":"10.1039\/b005390m"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b02605"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.468460"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1680720"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja00529a004"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.3c00695"},{"key":"e_1_2_8_57_1","unstructured":"\u00a0"},{"key":"e_1_2_8_58_2","doi-asserted-by":"publisher","DOI":"10.1080\/002689797171814"},{"key":"e_1_2_8_59_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.445514"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/j100312a018"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1528952"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp8111556"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1039\/b810189b"},{"key":"e_1_2_8_64_1","unstructured":"\u00a0"},{"key":"e_1_2_8_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00072a001"},{"key":"e_1_2_8_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/ct0499783"},{"key":"e_1_2_8_67_1","unstructured":"\u00a0"},{"key":"e_1_2_8_68_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.477483"},{"key":"e_1_2_8_69_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100180a030"},{"key":"e_1_2_8_70_1","volume-title":"Gaussian16, Revision A. 03","author":"Frisch M. J.","year":"2016"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.465106"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.462100"},{"key":"e_1_2_8_73_1","unstructured":"\u00a0"},{"key":"e_1_2_8_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar00127a002"},{"key":"e_1_2_8_75_2","doi-asserted-by":"publisher","DOI":"10.1016\/0009-2614(82)80335-7"},{"key":"e_1_2_8_76_1","unstructured":"\u00a0"},{"key":"e_1_2_8_77_2","doi-asserted-by":"publisher","DOI":"10.1080\/0144235031000124163"},{"key":"e_1_2_8_78_2","first-page":"229","volume-title":"Vibrational Dynamics of Molecules,","author":"Yu Q.","year":"2022"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0005081"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202400490","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T18:24:23Z","timestamp":1760293463000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202400490"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,3,15]]},"references-count":79,"journal-issue":{"issue":"27","published-print":{"date-parts":[[2024,5,14]]}},"alternative-id":["10.1002\/chem.202400490"],"URL":"https:\/\/doi.org\/10.1002\/chem.202400490","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,3,15]]},"assertion":[{"value":"2024-02-03","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-03-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202400490"}}