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The transformation displays broad scope including 27 cyclic and acyclic siloxydienes providing \u03b3\u2010fluoro compounds in 28\u201391\u2009% yield. Notably, the reported conditions are also suitable for the synthesis of challenging tertiary fluorides. The regioselectivity of the reaction was studied on a series of acyclic siloxydienes and was observed to be sensitive to the conformational flexibility of the substrate. Diversification of the \u03b3\u2010fluorocarbonyls demonstrates the promise of fluorine as a stereocontrol element.<\/jats:p>","DOI":"10.1002\/chem.202400493","type":"journal-article","created":{"date-parts":[[2024,3,5]],"date-time":"2024-03-05T09:35:22Z","timestamp":1709631322000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Remote Fluorination of \u03b1,\u03b2\u2010Unsaturated Carbonyls via Silyl Dienol Ethers"],"prefix":"10.1002","volume":"30","author":[{"given":"Daria V.","family":"Galaktionova","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Illinois\u2013Chicago  845 West Taylor St Chicago IL 60607 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sara Y.","family":"Siddiqui","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Illinois\u2013Chicago  845 West Taylor St Chicago IL 60607 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7005-3322","authenticated-orcid":false,"given":"Justin T.","family":"Mohr","sequence":"additional","affiliation":[{"name":"Department of Chemistry University of Illinois\u2013Chicago  845 West Taylor St Chicago IL 60607 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,3,22]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.0c00830"},{"key":"e_1_2_9_2_1","unstructured":"\u00a0"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1080\/14756360701425014"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jmedchem.1c00668"},{"key":"e_1_2_9_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.joc.0c02810"},{"key":"e_1_2_9_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201206566"},{"key":"e_1_2_9_6_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201206566"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrestox.0c00439"},{"key":"e_1_2_9_8_2","first-page":"1","volume":"13","author":"Chandra G.","year":"2023","journal-title":"Chem. 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