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Zn\u2010based SBUs are especially relevant in this case because they avoid quenching the chromophore's luminescence. We find that layer\u2010by\u2010layer spin\u2010coating using Zn acetate dihydrate and benzene\u20101,4\u2010dicarboxylic acid (H<jats:sub>2<\/jats:sub>BDC) and biphenyl\u20104,4\u2019\u2010dicarboxylic acid (H<jats:sub>2<\/jats:sub>BPDC) linkers readily produces crystalline thin films. However, analysis of the grazing\u2010incidence wide\u2010angle X\u2010ray scattering (GIWAXS) data reveals the structures of these films vary significantly with the linker, and with the metal\u2010to\u2010linker molar ratio used for fabrication. Under equimolar conditions, H<jats:sub>2<\/jats:sub>BPDC creates a type of structure like that proposed for SURMOF\u20102, whereas H<jats:sub>2<\/jats:sub>BDC generates a different metal\u2010hydroxide\u2010organic framework. Large excess of Zn<jats:sup>2+<\/jats:sup> ions causes the growth of layered zinc hydroxides, irrespective of the linker used. Density functional theory (DFT) calculations provide structural models with minimum total energy that are consistent with the experimentally observed diffractograms. In the broader sense, this work illustrates the importance in this field of careful structure determination, <jats:italic>e.\u2009g<\/jats:italic>., by utilizing GIWAXS and DFT simulations to determine the structure of the obtained crystalline metal\u2010organic thin films, such that properties can be rationally engineered and explained.<\/jats:p>","DOI":"10.1002\/chem.202400565","type":"journal-article","created":{"date-parts":[[2024,4,20]],"date-time":"2024-04-20T06:20:25Z","timestamp":1713594025000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Determining Structures of Layer\u2010by\u2010Layer Spin\u2010Coated Zinc Dicarboxylate\u2010Based Metal\u2010Organic Thin Films"],"prefix":"10.1002","volume":"30","author":[{"given":"Jan C.","family":"Fischer","sequence":"first","affiliation":[{"name":"Institute of Microstructure Technology Karlsruhe Institute of Technology  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robbin","family":"Steentjes","sequence":"additional","affiliation":[{"name":"Institute for Solid-State Physics, NAWI Graz Graz University of Technology  Petersgasse 16\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2561-2444","authenticated-orcid":false,"given":"Dong\u2010Hui","family":"Chen","sequence":"additional","affiliation":[{"name":"Institute of Functional Interfaces Karlsruhe Institute of Technology  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5469-048X","authenticated-orcid":false,"given":"Bryce S.","family":"Richards","sequence":"additional","affiliation":[{"name":"Institute of Microstructure Technology Karlsruhe Institute of Technology  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"},{"name":"Light Technology Institute Karlsruhe Institute of Technology  Engesserstrasse 13 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6502-1721","authenticated-orcid":false,"given":"Egbert","family":"Zojer","sequence":"additional","affiliation":[{"name":"Institute for Solid-State Physics, NAWI Graz Graz University of Technology  Petersgasse 16\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1078-3304","authenticated-orcid":false,"given":"Christof","family":"W\u00f6ll","sequence":"additional","affiliation":[{"name":"Institute of Functional Interfaces Karlsruhe Institute of Technology  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7327-7356","authenticated-orcid":false,"given":"Ian A.","family":"Howard","sequence":"additional","affiliation":[{"name":"Institute of Microstructure Technology Karlsruhe Institute of Technology  Hermann-von-Helmholtz-Platz\u20051 76344 Eggenstein-Leopoldshafen Germany"},{"name":"Light Technology Institute Karlsruhe Institute of Technology  Engesserstrasse 13 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,17]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C6CS00930A"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8AN00816G"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.08.024"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.6b00528"},{"key":"e_1_2_9_5_1","first-page":"1","volume":"8","author":"Zheng Y.","year":"2020","journal-title":"Adv. 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