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Compared to the vast number of boron\u2010nitrogen heterocycles, those that include phosphorus are less common. Furthermore, the use of phosphorus\u2010nitrogen triple bonds of any type to prepare such compounds is unprecedented. Here, we pair pyridyl hydrazonide ligands with phosphadiazonium cations and demonstrate that the chelated Mes*NP group is directly implicated in the photophysical and redox properties observed for the resulting heterocycles. In doing so, we introduce a novel building block for the production of phosphorus\u2010containing heterocycles that could find use in small molecule activation and catalysis or as the functional component of emerging organic electronics.<\/jats:p>","DOI":"10.1002\/chem.202400569","type":"journal-article","created":{"date-parts":[[2024,2,23]],"date-time":"2024-02-23T10:59:14Z","timestamp":1708685954000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Pnictogen\u2010Rich Heterocycles Derived from a Phosphadiazonium Cation"],"prefix":"10.1002","volume":"30","author":[{"given":"Shaun K.","family":"Milkovich","sequence":"first","affiliation":[{"name":"Department of Chemistry The University of Western Ontario (Western University)  1151 Richmond St. N. 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