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This study focuses on the synthesis of polar, amphoteric, amine\u2010oxide surfactants starting from biomass\u2010derived monosaccharides and demonstrating their potential in various applications. The synthesis involved a reductive amination of the sugars with an alkylamine and formaldehyde followed by oxidation to produce\n                    <jats:italic>N<\/jats:italic>\n                    \u2010oxide surfactants. These bio\u2010based surfactants exhibited promising properties, including high solubility, foamability, surface tension reduction, and critical micelle concentration. In particular,\n                    <jats:italic>\n                      <jats:bold>N<\/jats:bold>\n                    <\/jats:italic>\n                    <jats:bold>\u2010GalA1.10<\/jats:bold>\n                    and\n                    <jats:italic>\n                      <jats:bold>N<\/jats:bold>\n                    <\/jats:italic>\n                    <jats:bold>\u2010GalA1.12<\/jats:bold>\n                    showed comparable performance to commercial surfactants. Furthermore, these bio\u2010based surfactants demonstrated significantly lower skin irritation potential when compared to petrochemical\u2010derived counterparts like sodium laureth sulfate (SLES), making them potentially suitable for personal care products. The biodegradability assessment revealed that\n                    <jats:italic>\n                      <jats:bold>N<\/jats:bold>\n                    <\/jats:italic>\n                    <jats:bold>\u2010GalA1.12<\/jats:bold>\n                    exhibited good biodegradation, indicating its potential environmental compatibility. In conclusion, this study highlights the potential of bio\u2010based\n                    <jats:italic>N<\/jats:italic>\n                    \u2010oxide surfactants derived from monosaccharides as sustainable and skin\u2010friendly alternatives to traditional amphoteric surfactants, like cocamidopropyl betaine (CAPB).\n                  <\/jats:p>","DOI":"10.1002\/chem.202400986","type":"journal-article","created":{"date-parts":[[2024,5,5]],"date-time":"2024-05-05T22:34:07Z","timestamp":1714948447000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Synthesis and Performance of Bio\u2010Based Amphoteric Surfactants"],"prefix":"10.1002","volume":"30","author":[{"given":"Laura M.","family":"Jansen","sequence":"first","affiliation":[{"name":"Department of Synthetic Organic Chemistry Institute for Molecules and Materials Radboud University  Nijmegen The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pieter C.","family":"den Bakker","sequence":"additional","affiliation":[{"name":"Department of Synthetic Organic Chemistry Institute for Molecules and Materials Radboud University  Nijmegen The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Niek","family":"Venbrux","sequence":"additional","affiliation":[{"name":"Department of Synthetic Organic Chemistry Institute for Molecules and Materials Radboud University  Nijmegen The Netherlands"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kim W. 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