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Thus, the development of high\u2010performance n\u2010type organic semiconductors is of great importance for organic electronic devices and their integrated circuits. In recent years, azabenzannulated perylene diimide (PDI), as one of immense bay\u2010region\u2010annulated PDI derivatives, has drawn considerable attentions. However, the electronic mobilities of azabenzannulated PDI derivatives are barely satisfactory. In this contribution, the peripheral benzene ring in azabenzannulated PDI <jats:bold>2<\/jats:bold> was fused to the <jats:italic>ortho<\/jats:italic> position by intramolecular C\u2212H arylation cyclization. This endows the resultant azabenzannulated PDI <jats:bold>4<\/jats:bold> a planar configuration as well as electron deficient pentagonal ring. As a result, the electronic mobility of <jats:bold>4<\/jats:bold> is almost two orders of magnitude higher than that of the nonfused azabenzannulated PDI <jats:bold>2<\/jats:bold>. This work shall pave a new avenue in elevating the performance of azabenzannulated PDI in organic electronics.<\/jats:p>","DOI":"10.1002\/chem.202401074","type":"journal-article","created":{"date-parts":[[2024,5,2]],"date-time":"2024-05-02T22:26:10Z","timestamp":1714688770000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Ring Fusion Elevates the Electronic Mobility of Azabenzannulated Perylene Diimide"],"prefix":"10.1002","volume":"30","author":[{"given":"Fan","family":"Yang","sequence":"first","affiliation":[{"name":"School of Chemistry, Chemical Engineering and Life Science Wuhan University of Technology  No. 122 Luoshi Road 430070 Wuhan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Cui","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry, Chemical Engineering and Life Science Wuhan University of Technology  No. 122 Luoshi Road 430070 Wuhan 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