{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,28]],"date-time":"2026-08-28T22:49:20Z","timestamp":1787957360025,"version":"build-2784847793"},"reference-count":45,"publisher":"Wiley","issue":"35","license":[{"start":{"date-parts":[[2024,5,23]],"date-time":"2024-05-23T00:00:00Z","timestamp":1716422400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100006407","name":"Natural Science Foundation of Henan Province","doi-asserted-by":"publisher","award":["232300420141"],"award-info":[{"award-number":["232300420141"]}],"id":[{"id":"10.13039\/501100006407","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2024,6,20]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In this study, a series of H\u2010bonded arylamide foldamers bearing benzoselenadiazole ends with solvent\u2010responsive properties have been synthesized. In dichloromethane or dimethyl sulfoxide solvents, the molecules exhibit meniscus or linear structures, respectively, which can be attributed to the unique intramolecular hydrogen bonding behavior evidenced by 1D <jats:sup>1<\/jats:sup>H NMR and 2D NOESY spectra. UV\u2010vis spectroscopy experiments show that the absorption wavelength of H\u2010bonded arylamide foldamers are significantly red\u2010shifted due to the presence of benzoselenadiazole group. In addition, the crystal structures reveal that effective intermolecular dual Se\u2009\u22c5\u2009\u22c5\u2009\u22c5\u2009N interactions between benzoselenadiazole groups induce further assembly of the monomers. Remarkably, supramolecular linear and double helices structures are constructed under the synergistic induction of intramolecular hydrogen bonding and intermolecular chalcogen bonding. Additionally, 2D DOSY diffusion spectra and theoretical modelling based on density functional theory (DFT) are performed to explore the persistence of intermolecular Se\u2009\u22c5\u2009\u22c5\u2009\u22c5\u2009N interactions beyond the crystalline state.<\/jats:p>","DOI":"10.1002\/chem.202401150","type":"journal-article","created":{"date-parts":[[2024,4,19]],"date-time":"2024-04-19T10:19:53Z","timestamp":1713521993000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Benzoselenadiazole\u2010Functionalized H\u2010Bonded Arylamide Foldamers: Solvent\u2010Responsive Properties and Helix Self\u2010Assembly Directed by Chalcogen Bonding in Solid State"],"prefix":"10.1002","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8539-339X","authenticated-orcid":false,"given":"Chuan\u2010Zhi","family":"Liu","sequence":"first","affiliation":[{"name":"Engineering Research Centre for Optoelectronic Functional 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