{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T14:37:22Z","timestamp":1787236642617,"version":"build-2736575974"},"reference-count":26,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2024,7,15]],"date-time":"2024-07-15T00:00:00Z","timestamp":1721001600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100004837","name":"Ministerio de Ciencia e Innovaci\u00f3n","doi-asserted-by":"publisher","award":["RTI2018-095622-B-I00"],"award-info":[{"award-number":["RTI2018-095622-B-I00"]}],"id":[{"id":"10.13039\/501100004837","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2024,8]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The activity of catalytic nanoparticles is strongly dependent on their surface chemistry, which controls colloidal stability and substrate diffusion toward catalytic sites. In this work, we studied how the outer surface chemistry of nanostructured Rh(II)\u2010based metal\u2010organic cages or polyhedra (Rh\u2010MOPs) impacts their performance in homogeneous catalysis. Specifically, through post\u2010synthetic coordination of aliphatic imidazole ligands onto the exohedral Rh(II) axial sites of Rh\u2010MOPs, we solubilized a cuboctahedral Rh\u2010MOP in dichloromethane, thereby enabling its use as a homogeneous catalyst. We demonstrated that the presence of the coordinating ligand on the surface of the Rh\u2010MOP does not hinder its catalytic activity in styrene aziridination and cyclopropanation reactions, thanks to the dynamic Rh\u2010imidazole coordination bond. Finally, we used similar ligand exchange post\u2010synthetic reactions to develop a ligand\u2010mediated approach for precipitating the Rh\u2010MOP catalyst, facilitating the recovery and reuse of Rh\u2010MOPs as homogeneous catalysts.<\/jats:p>","DOI":"10.1002\/chem.202401661","type":"journal-article","created":{"date-parts":[[2024,5,23]],"date-time":"2024-05-23T08:39:20Z","timestamp":1716453560000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Recyclable Homogeneous Catalysis Enabled by Dynamic Coordination on Rhodium(II) Axial Sites of Metal\u2010Organic Polyhedra"],"prefix":"10.1002","volume":"30","author":[{"given":"Miguel","family":"S\u00e1nchez\u2010Fuente","sequence":"first","affiliation":[{"name":"Department of Inorganic Chemistry (Module 7) Facultad de Ciencias Universidad Aut\u00f3noma de Madrid  Madrid 28049 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Laura","family":"Hern\u00e1ndez\u2010L\u00f3pez","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology  Campus UAB Bellaterra, Barcelona 08193 Spain"},{"name":"Departament de Qu\u00edmica Facultat de Ciencies Universitat Autonoma de Barcelona  Bellaterra 08193 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1325-9161","authenticated-orcid":false,"given":"Daniel","family":"Maspoch","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology  Campus UAB Bellaterra, Barcelona 08193 Spain"},{"name":"Departament de Qu\u00edmica Facultat de Ciencies Universitat Autonoma de Barcelona  Bellaterra 08193 Spain"},{"name":"ICREA  Pg. Llu\u00eds Companys 23 08010 Barcelona Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rub\u00e9n","family":"Mas\u2010Ballest\u00e9","sequence":"additional","affiliation":[{"name":"Department of Inorganic Chemistry (Module 7) Facultad de Ciencias Universidad Aut\u00f3noma de Madrid  Madrid 28049 Spain"},{"name":"Institute for Advanced Research in Chemical Sciences (IAdChem) Universidad Aut\u00f3noma de Madrid  Madrid 28049 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Arnau","family":"Carn\u00e9\u2010S\u00e1nchez","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and The Barcelona Institute of Science and Technology  Campus UAB Bellaterra, Barcelona 08193 Spain"},{"name":"Departament de Qu\u00edmica Facultat de Ciencies Universitat Autonoma de Barcelona  Bellaterra 08193 Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,7,15]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00551"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/B916790K"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200705008"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr5005666"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00303"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature20771"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-022-00380-y"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC07034G"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.6b02091"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b13593"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10403"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202200357"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.202000955"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c12631"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA05592J"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1cc00030f"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201901668"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja016928o"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b02627"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/cs200597a"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(83)85028-0"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565-020-0652-2"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12146"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805340"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2017.02.002"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200804255"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202401661","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T21:00:30Z","timestamp":1760302830000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202401661"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,7,15]]},"references-count":26,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2024,8]]}},"alternative-id":["10.1002\/chem.202401661"],"URL":"https:\/\/doi.org\/10.1002\/chem.202401661","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,7,15]]},"assertion":[{"value":"2024-04-27","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-07-15","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202401661"}}