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One of the practical strategies is to copolymerize these bulk chemicals with epoxides to produce sulfur\u2010containing polymers. This approach contributes to improving the sustainability of polymer manufacturing, provides highly desired functional polymer materials, and has attracted much attention. However, these copolymerizations invariably exhibit the intensely complicated chemistry of O\/S exchange reaction, leading to sulfur\u2010containing polymers with diverse architectures. As the understanding of O\/S exchange continues to deepen, recent efforts have guided significant advances in the synthesis of CS<jats:sub>2<\/jats:sub>\u2010 and COS\u2010based polymers. 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