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However, effective catalysts operating at 70\u201390\u2009\u00b0C are rarely reported, limiting SCR scenarios to high\u2010temperature conditions. Herein, we report a unique MnO<jats:sub>2<\/jats:sub> nanofilament catalyst grown on activated semi\u2010coke synthesized via a one\u2010step in\u2005situ hydrothermal approach, which exhibits a stable and marked 100\u2009% conversion rate of NO to N<jats:sub>2<\/jats:sub> with 100\u2009% selectivity at 90\u2009\u00b0C, superior to the other prepared structures (nanowires, nanorods, and nanotubes). Temperature\u2010programmed desorption shows a large number of acid sites on MnO<jats:sub>2<\/jats:sub>(NFs)\/ASC, benefiting the formation of NH<jats:sub>4<\/jats:sub><jats:sup>+<\/jats:sup> ions. Meanwhile, diffuse reflectance infrared Fourier transform spectroscopy reveals the activation of NO with O<jats:sub>2<\/jats:sub> to form bidentate nitrate\/bridging nitrate NO<jats:sub>2<\/jats:sub> intermediates via bidentate nitrate species, triggering the Fast SCR with NH<jats:sub>3<\/jats:sub> at low temperatures. Such an effective, easy\u2010to\u2010prepare, and low\u2010cost catalyst paves a new pathway for low\u2010temperature SCR for a wide range of application scenarios.<\/jats:p>","DOI":"10.1002\/chem.202401803","type":"journal-article","created":{"date-parts":[[2024,8,7]],"date-time":"2024-08-07T05:34:12Z","timestamp":1723008852000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Low\u2010Temperature Reduction of NO<sub>x<\/sub> by NH<sub>3<\/sub> with Unity Conversion on Nanofilament MnO<sub>2<\/sub>\/Activated Semi\u2010Coke Catalyst"],"prefix":"10.1002","volume":"30","author":[{"given":"Beini","family":"He","sequence":"first","affiliation":[{"name":"Lab of Heat Mass Transfer &amp; Carbon Cycling Department of Energy and Resources Engineering College of Engineering Peking University  Beijing 100871 China"},{"name":"Beijing Key Laboratory for Solid Waste Utilization and Management Peking University  Beijing 100871 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