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Structure analysis revealed that <jats:bold>In\u2010MOF\u20101<\/jats:bold> has a three\u2010dimensional (3D) structure with a single metal core, while <jats:bold>In\u2010MOF\u20102<\/jats:bold> features an octahedron cage constructed by three kinds of metal clusters to further form a 3D structure. The fluorescence investigations showed that <jats:bold>In\u2010MOF\u20101<\/jats:bold> and <jats:bold>In\u2010MOF\u20102<\/jats:bold> are potential MOF\u2010based fluorescent sensors to detect acetone and Fe<jats:sup>3+<\/jats:sup> ions in EtOH or water with high sensitivity, excellent selectivity, recyclability and a low limit of detection. Moreover, the fluorescence mechanisms of I<jats:bold>n\u2010MOF\u20101<\/jats:bold> and <jats:bold>In\u2010MOF\u20102<\/jats:bold> toward acetone and Fe<jats:sup>3+<\/jats:sup> ions were further explained. In addition, <jats:bold>In\u2010MOF\u20102<\/jats:bold> has higher thermal and framework stability than <jats:bold>In\u2010MOF\u20101<\/jats:bold>. The activated <jats:bold>In\u2010MOF\u20102<\/jats:bold> presents a high BET surface area of 998.82\u2005m<jats:sup>2<\/jats:sup>g<jats:sup>\u22121<\/jats:sup> and a pore size distribution of 8 to 16\u2005\u00c5. At the same time, <jats:bold>In\u2010MOF\u20102<\/jats:bold> exhibits high selective CO<jats:sub>2<\/jats:sub> adsorption for CO<jats:sub>2<\/jats:sub>\/CH<jats:sub>4<\/jats:sub> and CO<jats:sub>2<\/jats:sub>\/N<jats:sub>2<\/jats:sub>, respectively. Furthermore, the adsorption sites and adsorption isotherms were predicted using grand canonical Monte Carlo (GCMC) simulations, and the adsorption energy of the lowest\u2010energy adsorption configuration was calculated using molecular dynamics (MD) simulations.<\/jats:p>","DOI":"10.1002\/chem.202402437","type":"journal-article","created":{"date-parts":[[2024,8,7]],"date-time":"2024-08-07T12:54:46Z","timestamp":1723035286000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Solvent\u2010Regulated Formation of Metal\/Metal\u2010Oxo Nodes in Two Indium Metal\u2010Organic Frameworks: Syntheses, Structures, Selective Gas Adsorption and Fluorescence Sensor Properties"],"prefix":"10.1002","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3667-3592","authenticated-orcid":false,"given":"Congyu","family":"Zuo","sequence":"first","affiliation":[{"name":"College of Material Science and Engineering Anhui University of Science and Technology  232001 Huainan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Qinqin","family":"Li","sequence":"additional","affiliation":[{"name":"College of Material Science and Engineering Anhui University of Science and Technology  232001 Huainan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mingzhu","family":"Dai","sequence":"additional","affiliation":[{"name":"College of Material Science and Engineering Anhui University of Science and Technology  232001 Huainan China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chenyang","family":"Fan","sequence":"additional","affiliation":[{"name":"College of Material Science and Engineering Anhui University of Science and Technology  232001 Huainan China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,10,2]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2023.123907"},{"key":"e_1_2_9_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2019.104154"},{"key":"e_1_2_9_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2021.122820"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202213915"},{"key":"e_1_2_9_6_1","unstructured":"\u00a0"},{"key":"e_1_2_9_7_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-022-04213-x"},{"key":"e_1_2_9_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2016.11.009"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.147394"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2022.05.046"},{"key":"e_1_2_9_11_1","unstructured":"\u00a0"},{"key":"e_1_2_9_12_2","doi-asserted-by":"publisher","DOI":"10.3390\/ijms24010369"},{"key":"e_1_2_9_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.microc.2023.108450"},{"key":"e_1_2_9_14_1","first-page":"2202023","volume":"41","author":"Pan M.-Q.","year":"2022","journal-title":"Chinese J. 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