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The valence isomers of benzene have also attracted synthetic chemists\u2019 attention due to their unique structures, bonding, and reactivity. We have been investigating boron\u2010nitrogen\u2010containing benzene valence isomers via photoisomerization of 1,2\u2010azaborines. In this contribution, we summarize recent developments of these highly strained BN\u2010heterocyclic compounds including their synthesis, characterization, proposed mechanism of formation, and their potential applications.<\/jats:p>","DOI":"10.1002\/chem.202402544","type":"journal-article","created":{"date-parts":[[2024,7,26]],"date-time":"2024-07-26T06:30:50Z","timestamp":1721975450000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Boron\u2010Nitrogen\u2010Containing Benzene Valence Isomers"],"prefix":"10.1002","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-9522-9521","authenticated-orcid":false,"given":"Tomoya","family":"Ozaki","sequence":"first","affiliation":[{"name":"Department of Chemistry Boston College  Chestnut Hill, Massachusetts 02467-3860 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3148-9147","authenticated-orcid":false,"given":"Shih\u2010Yuan","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Boston College  Chestnut Hill, Massachusetts 02467-3860 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,9,17]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja02231a009"},{"key":"e_1_2_8_3_1","unstructured":"\u00a0"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1139\/v08-110"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201200063"},{"key":"e_1_2_8_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201700562"},{"key":"e_1_2_8_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b09446"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00218A"},{"key":"e_1_2_8_9_1","unstructured":"\u00a0"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00878a045"},{"key":"e_1_2_8_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00905a022"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200805554"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja2097089"},{"key":"e_1_2_8_14_1","unstructured":"\u00a0"},{"key":"e_1_2_8_15_2","doi-asserted-by":"crossref","unstructured":"P.\u2005M. 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