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The addition reaction of \u03b1\u2010hydroxyphosphonates, derived from alkyl aryl\u2010 and diaryl ketones, with electrophiles such as phenyl vinyl sulfone, afforded phosphates having a tertiary alkyl group, which were readily convertible to the corresponding tertiary benzylic alcohols. This operationally simple protocol provides efficient complementary access to tertiary alcohols that are difficult to synthesize by conventional methods.<\/jats:p>","DOI":"10.1002\/chem.202402967","type":"journal-article","created":{"date-parts":[[2024,8,31]],"date-time":"2024-08-31T05:13:40Z","timestamp":1725081220000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Catalytic Generation of Benzyl Anions from Aryl Ketones Utilizing [1,2]\u2010Phospha\u2010Brook Rearrangement and Their Application to Synthesis of Tertiary Benzylic Alcohols"],"prefix":"10.1002","volume":"30","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7227-8579","authenticated-orcid":false,"given":"Azusa","family":"Kondoh","sequence":"first","affiliation":[{"name":"Research and Analytical Center for Giant Molecules Graduate School of Science Tohoku University  Aramaki, Aoba-ku Sendai 980-8578 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