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The single crystal X\u2010ray structure of complex\n                    <jats:bold>2<\/jats:bold>\n                    revealed the presence of discrete ions in the solid state. The complex (BICAAC)\u2009\u22c5\u2009BH\n                    <jats:sub>2<\/jats:sub>\n                    (OTf) (\n                    <jats:bold>3<\/jats:bold>\n                    ), obtained from the reaction of (BICAAC)\u2009\u22c5\u2009BH\n                    <jats:sub>3<\/jats:sub>\n                    with MeOTf, formed the corresponding boronium cations [(BICAAC)\u2009\u22c5\u2009BH\n                    <jats:sub>2<\/jats:sub>\n                    (L)]\n                    <jats:sup>+<\/jats:sup>\n                    (OTf)\n                    <jats:sup>\u2212<\/jats:sup>\n                    on reaction with Lewis bases (L= pyridine (\n                    <jats:bold>4<\/jats:bold>\n                    ) and DMAP (\n                    <jats:bold>5<\/jats:bold>\n                    )). Complexes\n                    <jats:bold>1<\/jats:bold>\n                    and\n                    <jats:bold>2<\/jats:bold>\n                    demonstrated notable catalytic activity in the hydrosilylation of a diverse array of carbonyls using 1.0\u2005mol\u2009% catalyst loading (achieving the highest turnover frequency (TOF\n                    <jats:sub>max<\/jats:sub>\n                    ) of up to 1200\u2005h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with benzaldehyde. A broad substrate scope has been presented for aldehydes and ketones decorated with various electron\u2010donating and withdrawing substituents along with this the hydrosilylation of a few\n                    <jats:italic>para<\/jats:italic>\n                    \u2010quinone methides has also been presented.\n                  <\/jats:p>","DOI":"10.1002\/chem.202403322","type":"journal-article","created":{"date-parts":[[2024,11,4]],"date-time":"2024-11-04T07:45:43Z","timestamp":1730706343000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Borenium Ion Equivalents Stabilized by BICAAC and Their Implementation as Catalysts in Hydrosilylation of Carbonyls"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1120-0847","authenticated-orcid":false,"given":"Manu","family":"Adhikari","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences Indian Institute of Science Education and Research Mohali  Knowledge City Sector 81 SAS Nagar, Mohali, Punjab 140306 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9103-780X","authenticated-orcid":false,"given":"Sandeep","family":"Kumar Thakur","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences Indian Institute of Science Education and Research Mohali  Knowledge City Sector 81 SAS Nagar, Mohali, Punjab 140306 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0806-3105","authenticated-orcid":false,"given":"Sanjay","family":"Singh","sequence":"additional","affiliation":[{"name":"Department of Chemical Sciences Indian Institute of Science Education and Research Mohali  Knowledge City Sector 81 SAS Nagar, Mohali, Punjab 140306 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,21]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"\u00a0"},{"key":"e_1_2_8_2_2","volume-title":"The Hydrosilylation Reaction. 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