{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T15:44:26Z","timestamp":1789141466216,"version":"build-2803163510"},"reference-count":42,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2024,11,16]],"date-time":"2024-11-16T00:00:00Z","timestamp":1731715200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100004349","name":"BASF","doi-asserted-by":"publisher","award":["INCOE (International Network of Centers of Excellence) project"],"award-info":[{"award-number":["INCOE (International Network of Centers of Excellence) project"]}],"id":[{"id":"10.13039\/100004349","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21872017, 21673027"],"award-info":[{"award-number":["21872017, 21673027"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,1,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Synthesis of renewable isoprene continues to attract significant interest, yet catalysts still need improvement for industrial applications. We report herein an efficient and novel Prins tandem approach for highly selective production of isoprene from bio\u2010based methanol and isobutene over Mo\u2010Fe\u2212O and MgO\/Mg(OH)<jats:sub>2<\/jats:sub> acid\u2010base bifunctional catalysts. Hydration decreases the number of strong basic sites O<jats:sup>2\u2212<\/jats:sup> ions and increases OH groups over MgO, thus improving the isoprene selectivity. Basic OH on Mg(OH)<jats:sub>2<\/jats:sub> promotes the Prins condensation of formaldehyde and isobutene, while acidic OH promotes dehydration of isoprenol to isoprene. Suitable contents and proportions of basic and acidic OH groups over Mg(OH)<jats:sub>2<\/jats:sub> increase isoprene selectivity and methanol conversion to 90 and 92\u2009% on the Mo\u2010Fe\u2212O+Mg(OH)<jats:sub>2<\/jats:sub> composite catalysts, respectively. It exhibits good recycling stability, with isoprene selectivity remaining 90\u2009% after five successive regenerations. DFT calculations reveal OH groups formed after hydration reduce the energy barrier of the H transfer step, thereby promoting the overall reaction.<\/jats:p>","DOI":"10.1002\/chem.202403375","type":"journal-article","created":{"date-parts":[[2024,10,30]],"date-time":"2024-10-30T03:10:01Z","timestamp":1730257801000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Highly Efficient and Selective Synthesis of Renewable Isoprene Over Mo\u2010Fe\u2010O and MgO\/Mg(OH)<sub>2<\/sub> Composite Catalysts"],"prefix":"10.1002","volume":"31","author":[{"given":"Lulu","family":"Xu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuo","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shikun","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Technology Xinjiang University  Urumqi 830017 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiangju","family":"Meng","sequence":"additional","affiliation":[{"name":"Department of Chemistry Zhejiang University  Hangzhou 310028 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Feng\u2010Shou","family":"Xiao","sequence":"additional","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Trees","family":"De Baerdemaeker","sequence":"additional","affiliation":[{"name":"Catalysis Research BASF SE  67056 Ludwigshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrei\u2010Nicolae","family":"Parvulescu","sequence":"additional","affiliation":[{"name":"Catalysis Research BASF SE  67056 Ludwigshafen Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1227-9769","authenticated-orcid":false,"given":"Weiping","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology  Dalian 116024 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,16]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200604348"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200703514"},{"key":"e_1_2_8_3_1","first-page":"100","volume":"1","author":"Ezinkwo G. 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