{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T14:37:19Z","timestamp":1787755039932,"version":"build-2784847793"},"reference-count":75,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2024,11,29]],"date-time":"2024-11-29T00:00:00Z","timestamp":1732838400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52122314, U22A20131, 52173014, 52273008 and 52361165657"],"award-info":[{"award-number":["52122314, U22A20131, 52173014, 52273008 and 52361165657"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,1,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Liquid\u2010crystallization\u2010driven self\u2010assembly (LCDSA) has recently emerged as an efficient strategy to create uniform one\u2010dimensional (1\u2010D), 2\u2010D and 3\u2010D nanostructures in a controlled manner. However, the examples of generation of uniform multi\u2010morphology nanostructures from solution self\u2010assembly of one single polymer sample are rare. Herein, we report the first example of preparation of multi\u2010morphology fried\u2010egg\u2010like nanostructures consisting of an inner spherical\/bowl\u2010like core of uniform size and platelets protruded from the core by LCDSA of PAMAM\u2010Azo<jats:sub>6<\/jats:sub> (PAMAM=polyamidoamine, Azo=azobenzene) in methanol. It is disclosed that the different aggregation rates for PAMAM\u2010Azo<jats:sub>6<\/jats:sub> with varying contents of Azo units spontaneously separated nucleation and growth stages, which led to the formation of inner spherical\/bowl\u2010like cores (\u201cseeds\u201d) firstly, followed by the formation of platelets protruded from the edges of inner core to give \u201cimperfect\u201d fried\u2010egg\u2010like nanostructures. Additional annealing of initially formed \u201cimperfect\u201d fried\u2010egg\u2010like micelles will promote the rearrangement of Azo units to give thermodynamically\u2010favored \u201cperfect\u201d fried\u2010egg\u2010shaped micelles with a uniform dimension both in the core and whole structure. This work not only provides an efficient strategy to create uniform multi\u2010morphology fried\u2010egg\u2010shaped nanostructures, but also reveals the essential impact of aggregation kinetics of liquid\u2010crystalline\u2010coil BCPs in the formation of multi\u2010morphology nanostructures.<\/jats:p>","DOI":"10.1002\/chem.202403430","type":"journal-article","created":{"date-parts":[[2024,11,14]],"date-time":"2024-11-14T22:24:25Z","timestamp":1731623065000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Liquid\u2010Crystallization\u2010Driven Self\u2010Assembly toward Uniform Multi\u2010Morphology Fried\u2010Egg\u2010Like Nanostructures"],"prefix":"10.1002","volume":"31","author":[{"given":"Longgang","family":"Xia","sequence":"first","affiliation":[{"name":"Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science and Engineering East China University of Science and Technology  130 Meilong Road Shanghai 200237 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Zhu","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science and Engineering East China University of Science and Technology  130 Meilong Road Shanghai 200237 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Binbin","family":"Xu","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science and Engineering East China University of Science and Technology  130 Meilong Road Shanghai 200237 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuyu","family":"Duan","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science and Engineering East China University of Science and Technology  130 Meilong Road Shanghai 200237 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyu","family":"Huang","sequence":"additional","affiliation":[{"name":"Macau University of Science and Technology Faculty of Medicine  Macau SAR 999078 People's Republic China"},{"name":"Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry University of Chinese Academy of Sciences  345 Lingling Road Shanghai 200032 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaoliang","family":"Lin","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science and Engineering East China University of Science and Technology  130 Meilong Road Shanghai 200237 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1034-9831","authenticated-orcid":false,"given":"Chun","family":"Feng","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science and Engineering East China University of Science and Technology  130 Meilong Road Shanghai 200237 People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,29]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35115c"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765-024-00429-1"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765-022-00212-0"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1007\/s42765-022-00236-6"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/nnano.2007.70"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-024-2009-7"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/am300840p"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2019.101195"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CC04825B"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c02402"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201609819"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c01092"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0PY01389G"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0PY00093K"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10118-023-2893-7"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c00643"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c00071"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja306264d"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0SC00596G"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b10199"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym13091481"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b09861"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202219067"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-10341-7"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c02395"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0CC00153H"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.08.003"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b02613"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b12735"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.2038"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.201900470"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.3c02673"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma502279b"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja510019s"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms4882"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202400312"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-03195-y"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201906214"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b10904"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.201800042"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.3c02287"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.9b02714"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.7b01437"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.2c01983"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.8b00070"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309914"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c01088"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c01020"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.2c00581"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.2c01570"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.8b00082"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201607059"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c00071"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.3c01639"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201604551"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.4c00524"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.3c02727"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c01789"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.0c00079"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.4c01809"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312724"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja953709s"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c00068"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06185"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3PY01006F"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3PY00368J"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.0c02521"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.8b01033"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10765-008-0415-z"},{"key":"e_1_2_8_70_1","doi-asserted-by":"crossref","unstructured":"C.\u2005M. Hansen 1967 39 104\u2013117.","DOI":"10.1097\/00006534-196701000-00056"},{"key":"e_1_2_8_71_1","first-page":"19","volume":"40","author":"Teas P.","year":"1968","journal-title":"J.\u2005J. Paint Technol."},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.202100213"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.1c00965"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.4c00634"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.1c00109"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202403430","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T08:56:35Z","timestamp":1760259395000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202403430"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,29]]},"references-count":75,"journal-issue":{"issue":"4","published-print":{"date-parts":[[2025,1,17]]}},"alternative-id":["10.1002\/chem.202403430"],"URL":"https:\/\/doi.org\/10.1002\/chem.202403430","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,29]]},"assertion":[{"value":"2024-09-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202403430"}}