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This led to multigram scale isolation of methanol obtained from CO<jats:sub>2<\/jats:sub> reduction <jats:italic>via<\/jats:italic> the hydrolysis of borylated methanol, this establishes the potential of Ce[N(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sub>3<\/jats:sub>(THF)<jats:sub>3<\/jats:sub> as an efficient homogeneous catalyst for the bulk scale methanol synthesis. A practical application of this catalytic system was also shown by reducing CO<jats:sub>2<\/jats:sub>\u2010containing motorbike exhaust efficiently and selectively. Further, C\u2212O bond activation of esters and epoxides using HBpin and 1\u20132\u2005mol\u2009% of Ce[N(SiMe<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sub>3<\/jats:sub>(THF)<jats:sub>3<\/jats:sub> at 60\u2009\u00b0C afforded the borylated alcohols in good to excellent yields, which can easily be hydrolysed to the eco\u2010friendly corresponding alcohol. The stoichiometric experiments were performed to prove the formation of <jats:italic>in\u2010situ<\/jats:italic> generated cerium hydride [Ce]\u2010H as an active catalyst.<\/jats:p>","DOI":"10.1002\/chem.202403449","type":"journal-article","created":{"date-parts":[[2025,1,9]],"date-time":"2025-01-09T00:48:58Z","timestamp":1736383738000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Ce[N(SiMe<sub>3<\/sub>)<sub>2<\/sub>]<sub>3<\/sub>(THF)<sub>3<\/sub>\u2010Catalyzed Hydroboration of CO<sub>2<\/sub>, Esters and Epoxides with Pinacolborane: Selective Synthesis of Methanol in Multigram Scale"],"prefix":"10.1002","volume":"31","author":[{"given":"Md Jabed","family":"Hossain","sequence":"first","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER), Pune  Dr. Homi Bhabha Road, Pashan Pune 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Brij Kumar","family":"Shah","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER), Pune  Dr. Homi Bhabha Road, Pashan Pune 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Soumya Ranjan","family":"Dash","sequence":"additional","affiliation":[{"name":"Physical and Materials Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road, Pashan 411008 Pune India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"family":"Kashish","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER), Pune  Dr. Homi Bhabha Road, Pashan Pune 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kumar","family":"Vanka","sequence":"additional","affiliation":[{"name":"Physical and Materials Chemistry Division CSIR-National Chemical Laboratory  Dr. Homi Bhabha Road, Pashan 411008 Pune India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6844-3954","authenticated-orcid":false,"given":"Shabana","family":"Khan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Science Education and Research (IISER), Pune  Dr. Homi Bhabha Road, Pashan Pune 411008 India"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2025,1,21]]},"reference":[{"key":"e_1_2_9_1_1","unstructured":"\u00a0"},{"key":"e_1_2_9_2_2","doi-asserted-by":"publisher","DOI":"10.1080\/01614949408013931"},{"key":"e_1_2_9_3_2","doi-asserted-by":"crossref","unstructured":"J. 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