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In this work, a series of ionic porous organic polymers (IPOPs) with different basic\u2010functionalized anions were successfully synthesized and adjusted to have certain BET surface areas and high contents of ion sites by post\u2010modification. These basic\u2010functionalized IPOPs could exhibit excellent catalytic performance for carboxylative cyclization of CO\n                    <jats:sub>2<\/jats:sub>\n                    at 30\u2009\u00b0C and 1\u2005bar in presence of silver salts, eliminating the use of the extra organic bases. In the whole catalytic reaction, the basic\u2010functionalized anions could play triple roles: enriching CO\n                    <jats:sub>2<\/jats:sub>\n                    for further transformation, activating the hydroxyl groups of substrates to improve the catalytic performance, while coordinating with Ag atom to stabilize and regenerate catalyst. Notably, the catalytic system of DCX\u20104\u2010Tet\/Ag\n                    <jats:sub>2<\/jats:sub>\n                    O exhibited excellent recyclability, and the yield of \u03b1\u2010alkylidene cyclic carbonate was well maintained at 99\u2009% after 5\u2005cycles. To the best of our knowledge, the catalytic system was the first example of basic\u2010functionalized IPOPs that played multiple roles for highly efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    cyclization under mild conditions without any extra organic bases.\n                  <\/jats:p>","DOI":"10.1002\/chem.202403476","type":"journal-article","created":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T07:02:06Z","timestamp":1732086126000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Basic\u2010Functionalized Ionic Porous Organic Polymers: Triple Roles in One for Highly Efficient and Recyclable Carboxylative Cyclization of CO\n                    <sub>2<\/sub>\n                    under Mild Conditions"],"prefix":"10.1002","volume":"31","author":[{"given":"Han","family":"Tao","sequence":"first","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weiqi","family":"Mao","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lili","family":"Jiang","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiaoxin","family":"Xiao","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenyu","family":"Zhao","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kaili","family":"Wang","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaowei","family":"Zhang","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayi","family":"Bai","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoran","family":"Li","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for Frontier Technologies Zhejiang University  Hangzhou 310027 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3258-8887","authenticated-orcid":false,"given":"Congmin","family":"Wang","sequence":"additional","affiliation":[{"name":"National Key Laboratory of Biobased Transportation Fuel Technology Department of Chemistry Center of Chemistry for 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