{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T00:58:10Z","timestamp":1789693090531,"version":"4.0.1"},"reference-count":33,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2025,1,15]],"date-time":"2025-01-15T00:00:00Z","timestamp":1736899200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/100004366","name":"Chevron","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100004366","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,2,17]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>CO<jats:sub>2<\/jats:sub>\u2010based hydroesterification is an attractive route to produce value added ester compounds, which could replace widely used CO\u2010based hydroesterification processes if sufficient catalytic technologies are developed. One path to CO<jats:sub>2<\/jats:sub>\u2010based hydroesterification could proceed through an organoformate intermediate, which is then used in olefin hydroesterification to generate the desirable esters. This route opens the possibility of creating a net CO<jats:sub>2<\/jats:sub>\u2010based hydroesterification process using tandem catalytic systems for CO<jats:sub>2<\/jats:sub> hydrogenation to organoformate paired with formate\u2010olefin hydroesterification. The tandem use of tripodal phosphine ruthenium(II) and 1,2\u2010bis(di\u2010tert\u2010butylphosphinomethyl)benzene palladium catalysts were found to successfully produce methyl nonanoate from CO<jats:sub>2<\/jats:sub>, H<jats:sub>2<\/jats:sub>, methanol and 1\u2010octene in a single\u2010stage batch process. The CO<jats:sub>2<\/jats:sub>\u2010based hydroesterification catalysis efficiency was found to be largely limited by the productivity of organoformate generation and competitive 1\u2010octene reduction. Catalytic yields of methyl nonanoate can be enhanced by adjustments in reaction procedures, including the use of a two\u2010stage batch reaction process or delayed introduction of 1\u2010octene, achieving a yield of up to 32\u2009%. Under select conditions, control experiments indicate yields of methyl nonanoate can be improved to <jats:italic>ca<\/jats:italic> 75\u2009%. Preliminary studies indicate significant interplay between the two ligands employed in the molecular tandem catalytic systems and establish the first catalytic protocol for the selective CO<jats:sub>2<\/jats:sub>\u2010based hydroesterification of olefins via organoformates.<\/jats:p>","DOI":"10.1002\/chem.202403505","type":"journal-article","created":{"date-parts":[[2025,1,6]],"date-time":"2025-01-06T11:23:40Z","timestamp":1736162620000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Catalytic Conversion of Carbon Dioxide to Long Chain Esters via Formate Hydroesterification"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0009-0004-3157-3730","authenticated-orcid":false,"given":"Kyler","family":"Virtue","sequence":"first","affiliation":[{"name":"The Department of Chemistry The University of Missouri  Columbia, Missouri 65211 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