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The reaction of\n                    <jats:bold>3<\/jats:bold>\n                    with CO\n                    <jats:sub>2<\/jats:sub>\n                    yielded a trimeric carbonate complex [{L\n                    <jats:sup>Ph<\/jats:sup>\n                    Ga(CO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>3<\/jats:sub>\n                    {\u03bc\u2010K\n                    <jats:sub>9<\/jats:sub>\n                    (THF)\n                    <jats:sub>6<\/jats:sub>\n                    }] (\n                    <jats:bold>4<\/jats:bold>\n                    ) and a dinuclear oxo\u2010carbonate complex [K\n                    <jats:sub>2<\/jats:sub>\n                    (THF)\n                    <jats:sub>6<\/jats:sub>\n                    ][L\n                    <jats:sup>Ph<\/jats:sup>\n                    Ga(\u03bc\u2010CO\n                    <jats:sub>3<\/jats:sub>\n                    )(\u03bc\u2010O)GaL\n                    <jats:sup>Ph<\/jats:sup>\n                    ] (\n                    <jats:bold>5<\/jats:bold>\n                    ) in one pot through reductive disproportionation of CO\n                    <jats:sub>2<\/jats:sub>\n                    . For CS\n                    <jats:sub>2<\/jats:sub>\n                    , two ethenetetrathiolate gallium complexes, [M\n                    <jats:sub>2<\/jats:sub>\n                    (Solv)\n                    <jats:sub>4<\/jats:sub>\n                    ][L\n                    <jats:sup>Ph<\/jats:sup>\n                    Ga(\u03bc\u2010C\n                    <jats:sub>2<\/jats:sub>\n                    S\n                    <jats:sub>4<\/jats:sub>\n                    )GaL\n                    <jats:sup>Ph<\/jats:sup>\n                    ] (M=Na, Solv=THF,\n                    <jats:bold>6<\/jats:bold>\n                    ; M=K, Solv=DME,\n                    <jats:bold>7<\/jats:bold>\n                    ), were obtained via reductive coupling of CS\n                    <jats:sub>2<\/jats:sub>\n                    . In the case of COS, disproportionation gave a disulfide\u2010bridged complex [K\n                    <jats:sub>2<\/jats:sub>\n                    (THF)\n                    <jats:sub>6<\/jats:sub>\n                    ] [L\n                    <jats:sup>Ph<\/jats:sup>\n                    Ga(\u03bc\u2010S)\n                    <jats:sub>2<\/jats:sub>\n                    GaL\n                    <jats:sup>Ph<\/jats:sup>\n                    ] (\n                    <jats:bold>8<\/jats:bold>\n                    ) at room temperature, but a dithiocarbonate [Na\n                    <jats:sub>2<\/jats:sub>\n                    (THF)\n                    <jats:sub>5<\/jats:sub>\n                    ][L\n                    <jats:sup>Ph<\/jats:sup>\n                    Ga(S\n                    <jats:sub>2<\/jats:sub>\n                    CO)]\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>9<\/jats:bold>\n                    ) at low temperature, the latter being the first example of dithiocarbonates of\n                    <jats:italic>p<\/jats:italic>\n                    \u2010block elements.\n                  <\/jats:p>","DOI":"10.1002\/chem.202403652","type":"journal-article","created":{"date-parts":[[2024,11,23]],"date-time":"2024-11-23T09:04:37Z","timestamp":1732352677000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["Activation of CO\n                    <sub>2<\/sub>\n                    , CS\n                    <sub>2<\/sub>\n                    , and COS by \u03b1\u2010Diimine\u2010Stabilized Gallylenes"],"prefix":"10.1002","volume":"31","author":[{"given":"Meng","family":"Guo","sequence":"first","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ben","family":"Dong","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Qu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenzhou","family":"Sun","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Yang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanchao","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Medicinal Molecule Science and Pharmaceutics Engineering Ministry of Industry and Information Technology School of Chemistry and Chemical Engineering Beijing Institute of Technology  Beijing 100081 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Igor L.","family":"Fedushkin","sequence":"additional","affiliation":[{"name":"G. 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