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The radical was obtained in five consecutive steps from commercially available starting materials with a total yield of 34\u2009%; key steps are Suzuki couplings and cyclizing S\n                    <jats:sub>E<\/jats:sub>\n                    Ar reactions. Mesityl substituents at the five\u2010membered rings ensure the stability of the radical. This cyclopenta\u2010fused polyaromatic hydrocarbon (CP\u2010PAH) was characterized by EPR and UV\/Vis spectroscopy and by cyclic voltammetry. Quantum chemical calculation disclosed further properties and led to simulated spectra (spin densities, aromaticity, orbital energies, and UV\/Vis\/NIR). This radical is best described with the unpaired electron centered in the outer five\u2010membered rings; these resonance formulas show the largest number of fully intact benzene rings. Its triradical character was computed to be very small and can be neglected. The five\u2010membered rings show notable antiaromatic character, especially in the central ring. The constitution of the radical could be further substantiated by X\u2010ray crystallographic analysis of its direct precursor.\n                  <\/jats:p>","DOI":"10.1002\/chem.202403670","type":"journal-article","created":{"date-parts":[[2024,12,6]],"date-time":"2024-12-06T11:44:34Z","timestamp":1733485474000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["A Stable Carbon\u2010Centered Radical Showing Six Amphoteric Redox States"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-8563-9101","authenticated-orcid":false,"given":"Ali S.","family":"Acan","sequence":"first","affiliation":[{"name":"Institute of Organic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstra\u00dfe\u200512 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-5004-989X","authenticated-orcid":false,"given":"Jonas O.","family":"Wenzel","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstra\u00dfe\u200512 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6615-1712","authenticated-orcid":false,"given":"Frank","family":"Breher","sequence":"additional","affiliation":[{"name":"Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstra\u00dfe\u200512 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7881-6905","authenticated-orcid":false,"given":"Joachim","family":"Podlech","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry Karlsruhe Institute of Technology (KIT)  Kaiserstra\u00dfe\u200512 76131 Karlsruhe Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,17]]},"reference":[{"key":"e_1_2_3_1_1","unstructured":"\u00a0"},{"key":"e_1_2_3_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19700821309"},{"key":"e_1_2_3_3_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197005271"},{"key":"e_1_2_3_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.197719770615"},{"key":"e_1_2_3_5_2","first-page":"3","volume-title":"Polycyclic Arenes and Heteroarenes: Synthesis, Properties, and Applications","author":"Das S.","year":"2016"},{"key":"e_1_2_3_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6SC01795A"},{"key":"e_1_2_3_7_2","volume":"2","author":"Das S.","year":"2017","journal-title":"Phys. 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