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A key factor in the efficiency of this process lies in the interaction between the metal catalyst and its support. Metal\u2010Organic Frameworks (MOFs) have emerged as highly effective platforms due to their tunable structures, large surface areas, and ability to form stable interfaces with single\u2013atom metals or metal nanoparticles. These metal\u2010MOF interfaces are crucial for stabilizing active sites, preventing sintering, and enhancing catalytic performance. In this concept paper, we explore the role of these interfaces in promoting CO\u2082 hydrogenation, focusing on Cu\u2212Zn, Cu\u2212Zr, and Zn\u2212Zr interfaces. The formation of strong interactions between metal sites and MOF nodes enables precise control over the dispersion and electronic environment of the active species, significantly improving methanol selectivity and long\u2010term stability. 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