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However, bulk synthesis remains a challenging task due to the stability of the N\n                    <jats:sub>2<\/jats:sub>\n                    molecule. In this study, we introduce a simple and scalable approach for synthesizing nitride bulk materials. Moderate reaction temperatures are achieved by using reactive starting materials, slow and continuous mixing of the starting materials, and by dissipating heat generated during the reaction. The impact on the synthesis of using different starting materials as nitrogen source and the influence of a flux were examined.\n                    <jats:italic>\u03b3\u2010<\/jats:italic>\n                    Sn\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    was selected as the model compound. The synthesis of pure\n                    <jats:italic>\u03b3<\/jats:italic>\n                    \u2010Sn\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    bulk material on a large scale has still been a challenge, although a few synthesis methods were already described in the literature. Here we synthesized\n                    <jats:italic>\u03b3<\/jats:italic>\n                    \u2010Sn\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    by metathesis reaction of argon\u2010diluted SnCl\n                    <jats:sub>4<\/jats:sub>\n                    with Li\n                    <jats:sub>3<\/jats:sub>\n                    N, Mg\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    or Ca\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    as nitrogen sources. Products were characterized by powder X\u2010ray diffraction, scanning and transmission electron microscopy, energy\u2010dispersive X\u2010ray spectroscopy, dynamic flash combustion analysis, hot gas extraction analysis, X\u2010ray photoelectron spectroscopy, M\u00f6ssbauer spectroscopy and X\u2010ray absorption and emission spectroscopy. Additionally, single\u2010crystal diffraction data of\n                    <jats:italic>\u03b3\u2010<\/jats:italic>\n                    Sn\u2083N\u2084, previously unavailable, were successfully collected.\n                  <\/jats:p>","DOI":"10.1002\/chem.202403745","type":"journal-article","created":{"date-parts":[[2024,11,18]],"date-time":"2024-11-18T11:24:39Z","timestamp":1731929079000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Scalable Bulk Synthesis of Phase\u2010Pure\n                    <i>\u03b3\u2010<\/i>\n                    Sn\n                    <sub>3<\/sub>\n                    N\n                    <sub>4<\/sub>\n                    as a Model for an Argon\u2010Flow\u2010Mediated Metathesis 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